We　describe　in　this　paper　the　synthesis　and　the　characterization　of　Li4Ti5O12-reduced　graphene　oxide　(LTO-RGO)　composite　and　demonstrate　their　use　as　hybrid　supercapacitor,　which　is　consist　of　an　LTO　negative　electrode　and　activate　carbon　(AC)　positive　electrode.　The　LTO-RGO　composites　were　synthesized　using　a　simple,　one-step　process,　in　which　lithium　sources　and　titanium　sources　were　dissolved　in　a　graphene　oxide　(GO)　suspension　and　then　thermal　treated　in　N-2.　The　lithium-ion　battery　with　LTO-RGO　composite　anode　electrode　revealed　higher　discharge　capacity　(167　mAh　g(-1)　at　0.2　C)　and　better　capacity　retention　(67%)　than　the　one　with　pure　LTO.　Meanwhile,　compared　with　the　AC//LTO　supercapacitor,　the　AC//LTO-RGO　hybrid　supercapacitor　exhibits　higher　energy　density　and　power　density.　Results　show　that　the　LTO-RGO　composite　is　a　very　promising　anode　material　for　hybrid　supercapacitor.