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Author:

Li, Biao (Li, Biao.) | Shao, Ruiwen (Shao, Ruiwen.) | Yan, Huijun (Yan, Huijun.) | An, Li (An, Li.) | Zhang, Bin (Zhang, Bin.) | Wei, Hang (Wei, Hang.) | Ma, Jin (Ma, Jin.) | Xia, Dingguo (Xia, Dingguo.) | Han, Xiaodong (Han, Xiaodong.) (Scholars:韩晓东)

Indexed by:

SCIE

Abstract:

Lithium-rich layered oxides are considered as promising cathode materials for Li-ion batteries with high energy density due to their higher capacity as compared with the conventional LiMO2 (e.g., LiCoO2, LiNiO2, and LiNi1/3Co1/3Mn O-1/3(2)) layered oxides. However, why lithium-rich layered oxides exhibit high capacities without undergoing a structural collapse for a certain number of cycles has attracted limited attention. Here, based on the model of Li2RuO3, it is uncovered that the mechanism responsible for the structural integrity shown by lithium-rich layered oxides is realized by the fl exible local structure due to the presence of lithium atoms in the transition metal layer, which favors the formation of O-2(2-)-like species, with the aid of in situ extended X-ray absorption fi ne structure (EXAFS), in situ energy loss spectroscopy (EELS), and density functional theory (DFT) calculation. This fi nding will open new scope for the development of high-capacity layered electrodes.

Keyword:

Author Community:

  • [ 1 ] [Li, Biao]Peking Univ, Coll Engn, Beijing Key Lab Theory & Technol Adv Batteries Ma, Beijing 100871, Peoples R China
  • [ 2 ] [Yan, Huijun]Peking Univ, Coll Engn, Beijing Key Lab Theory & Technol Adv Batteries Ma, Beijing 100871, Peoples R China
  • [ 3 ] [An, Li]Peking Univ, Coll Engn, Beijing Key Lab Theory & Technol Adv Batteries Ma, Beijing 100871, Peoples R China
  • [ 4 ] [Wei, Hang]Peking Univ, Coll Engn, Beijing Key Lab Theory & Technol Adv Batteries Ma, Beijing 100871, Peoples R China
  • [ 5 ] [Ma, Jin]Peking Univ, Coll Engn, Beijing Key Lab Theory & Technol Adv Batteries Ma, Beijing 100871, Peoples R China
  • [ 6 ] [Xia, Dingguo]Peking Univ, Coll Engn, Beijing Key Lab Theory & Technol Adv Batteries Ma, Beijing 100871, Peoples R China
  • [ 7 ] [Shao, Ruiwen]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 8 ] [Zhang, Bin]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 9 ] [Han, Xiaodong]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 夏定国 韩晓东

    [Xia, Dingguo]Peking Univ, Coll Engn, Beijing Key Lab Theory & Technol Adv Batteries Ma, Beijing 100871, Peoples R China;;[Han, Xiaodong]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2016

Issue: 9

Volume: 26

Page: 1330-1337

1 9 . 0 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:305

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 131

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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