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Author:

Rong, Zhen (Rong, Zhen.) | Xiao, Rui (Xiao, Rui.) | Wang, Chongwen (Wang, Chongwen.) | Wang, Donggen (Wang, Donggen.) | Wang, Shengqi (Wang, Shengqi.)

Indexed by:

EI Scopus SCIE

Abstract:

Plasmonic Ag core satellite nanostructures were synthesized by utilizing the ultrathin silica shell as a spacer to generate a tunable nanogap between the Ag core and satellites. To synthesize the nanoparticles, Ag nanoparticles (Ag NPs) with a diameter of similar to 60 nm were synthesized as cores, on which Raman dyes were adsorbed and then tunable ultrathin silica shells from 2.0 to 6.5 nm were coated, followed by the deposition of Ag NPs as satellites onto the silica surface. The relationships between the SERS signal and the important parameters, including the satellite diameter and the nanogap distance, were studied by experimental methods and theoretical calculations. The maximum SERS intensity of the core satellite nanoparticles was over 14.6 times stronger than that of the isolated Raman-encoded Ag/PATP@SiO2 NP. The theoretical calculations indicated that the local maximum calculated enhancement factor (EF) of the hot spots with a 2.0 nm nanogap was 9.5 x 10(5). The well-defined Ag core satellite nanostructures have a high structural uniformity and an anomalously strong electromagnetic enhancement for highly quantitative SERS, leading to a better understanding of hot spot formation and providing new insights into the optimal design and synthesis of the hot SERS nanostructures in a controlled manner.

Keyword:

Author Community:

  • [ 1 ] [Rong, Zhen]Beijing Inst Radiat Med, Beijing Key Lab New Mol Diag Technol Infect Dis, Beijing 100850, Peoples R China
  • [ 2 ] [Xiao, Rui]Beijing Inst Radiat Med, Beijing Key Lab New Mol Diag Technol Infect Dis, Beijing 100850, Peoples R China
  • [ 3 ] [Wang, Chongwen]Beijing Inst Radiat Med, Beijing Key Lab New Mol Diag Technol Infect Dis, Beijing 100850, Peoples R China
  • [ 4 ] [Wang, Shengqi]Beijing Inst Radiat Med, Beijing Key Lab New Mol Diag Technol Infect Dis, Beijing 100850, Peoples R China
  • [ 5 ] [Wang, Chongwen]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Donggen]Inst Transfus Med, Beijing 100850, Peoples R China

Reprint Author's Address:

  • [Wang, Donggen]Inst Transfus Med, Beijing 100850, Peoples R China

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Source :

LANGMUIR

ISSN: 0743-7463

Year: 2015

Issue: 29

Volume: 31

Page: 8129-8137

3 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:253

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 33

SCOPUS Cited Count: 40

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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