Thin　films　with　one-dimensional　nanostructures　and　unique　physical　properties　are　potential　candidates　for　next-generation　high-performance　electronic,　optoelectronic,　and　electromechanical　systems.　Here　we　report　that　large-scale　oriented　silver　nanowire　films　can　be　prepared　by　controlling　the　coffee-ring　effect　through　tilting　the　substrates　during　the　film　deposition.　The　anisotropic　optical　properties　of　the　orientated　silver　nanowire　film　are　researched　here.　Surface　enhanced　Raman　scattering　(SERS)　spectra　were　recorded　from　Rhodamine　6G　adsorbed　on　the　silver　nanowire　films.　The　SERS　spectra　showed　striking　polarization　dependence　according　to　the　angle　between　the　long　axes　of　the　nanowires　and　the　light　polarization.　At　the　vertical　excitation　(i.e.,　light　polarization　forms　a　90　degrees　angle　to　the　long　axes　of　the　nanowires),　the　SERS　intensity　reaches　a　maximum.　Minimum　intensities　were　obtained　at　a　parallel　excitation.　The　three-dimensional　finite　element　method　was　used　to　give　an　in-depth　explanation　of　these　properties.　Angular　resolution　fluorescence　is　also　studied.　The　fluorescence　displays　an　angle-dependence　similar　to　the　Raman　activities.　Optical　properties　were　also　investigated　through　the　polarization　of　reflectivity　spectra.　The　reflectivity　is　smaller　when　the　incident　light　is　polarized　parallel　to　the　orientation　direction.　As　the　wavelength　increases,　the　reflectivity　increases　when　the　polarization　of　incident　light　is　perpendicular　to　the　orientation　direction.　When　the　wavelength　is　greater　than　870　nm,　the　amplitude　can　be　up　to　doubled.　Our　study　indicates　that　this　technique　is　promising　in　the　production　of　large-scale　orientated　silver　nanowire　films　with　anisotropic　optical　properties　for　high-performance　electronic,　optoelectronic,　and　electromechanical　systems.