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Structure, magnetic properties, and thermal stability of ternary Sm1-x Tm (x) Co-5 compounds were studied via X-ray diffraction (XRD), thermal magnetic analysis (TMA), and magnetic measurements. XRD results show that all the compounds have a main phase of hexagonal CaCu5-type crystal structure with small amount of impurity phases; increasing Tm content is associated with contraction of the hexagonal unit cell in the direction of the c axis and expansion of the a and b parameters. TMA results indicate that the Curie temperature (T (C)) of Sm1-x Tm (x) Co-5 compounds gets higher with the increase in Tm content. Magnetic measurements show that both the magnetic anisotropy field (H (A)) and the magnetization at an applied field of 7 T (M (7 T)) decrease with the increase of Tm content. However, the thermal stability of both the H (A) and M (7 T) of all the Tm doped compounds is remarkably improved compared with that of the pure SmCo5 compound, leading to the result that both the M (7 T) and H (A) of Sm0.8Tm0.2Co5.2 are higher than those of SmCo5 compound at 473 K, which indicates the good potential of Tm doped compound in the practical applications at elevated temperature.
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RARE METALS
ISSN: 1001-0521
Year: 2014
Issue: 2
Volume: 33
Page: 176-179
8 . 8 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:341
JCR Journal Grade:2
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 7
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 5
Affiliated Colleges: