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Author:

Liu, Baixiong (Liu, Baixiong.) | Wang, Jinshu (Wang, Jinshu.) (Scholars:王金淑) | Wu, Junshu (Wu, Junshu.) | Li, Hongyi (Li, Hongyi.) (Scholars:李洪义) | Wang, Hong (Wang, Hong.) | Li, Zhifei (Li, Zhifei.) | Zhou, Meiling (Zhou, Meiling.) | Zuo, Tieyong (Zuo, Tieyong.) (Scholars:左铁镛)

Indexed by:

EI Scopus SCIE

Abstract:

Enhancing surface area is one of the efficient ways to improve photochromic sensitivity of WO3 center dot 0.33H(2)O. Hierarchical WO3 center dot 0.33H(2)O mesoporous nanorod assemblies were synthesized via proton exchange by adjusting the concentration of Na2WO4 center dot 2H(2)O. When the concentration of Na2WO4 center dot 2H(2)O is 2.0 g L-1, mesoporous nanorods with 10 similar to 20 nm in diameter and an average pores size of about 4 nm were obtained. The novel WO3 center dot 0.33H(2)O porous structure possesses highly photochromic sensitivity and fatigue resistance properties. It exhibits visible-light-driven photochromic response due to large specific surface area originated from the mesoporous structure. The formation of mesopores is due to the volume decreasing in the transformation process from WO3 center dot H2O to WO3 center dot 0.33H(2)O. (c) 2012 Elsevier B.V. All rights reserved.

Keyword:

Microstructure Photochromism Porous materials Proton exchange WO3 center dot 0.33H(2)O

Author Community:

  • [ 1 ] [Liu, Baixiong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Jinshu]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wu, Junshu]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Hongyi]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Hong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Li, Zhifei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Zhou, Meiling]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Zuo, Tieyong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 9 ] [Liu, Baixiong]Jiangxi Univ Sci & Technol, Inst Res & Engn, Ganzhou 341000, Jiangxi, Peoples R China

Reprint Author's Address:

  • 王金淑

    [Wang, Jinshu]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

MATERIALS LETTERS

ISSN: 0167-577X

Year: 2013

Volume: 91

Page: 334-337

3 . 0 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 32

SCOPUS Cited Count: 36

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 10

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