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Author:

Yue, M. (Yue, M..) (Scholars:岳明) | Li, Z. Q. (Li, Z. Q..) | Liu, X. B. (Liu, X. B..) | Xu, H. (Xu, H..) | Liu, D. M. (Liu, D. M..) (Scholars:刘丹敏) | Zhang, J. X. (Zhang, J. X..)

Indexed by:

EI Scopus SCIE

Abstract:

Crystal structure, magnetocaloric effect and magnetic transition in bulk Mn1.1Fe0.9P0.8Ge0.2 compound have been studied by X-ray diffraction, magnetic measurements and Landau-Ginzberg theory. Mn1.1Fe0.9P0.8Ge0.2 compound crystallizes in a hexagonal Fe2P-type structure with lattice constants of a = 6.0789(10) angstrom and c = 3.4674(9) angstrom. The compound exhibits giant magnetocaloric effect with maximum magnetic entropy change of 61.8 J/kg K in a field change from 0 to 5T around its Curie temperature of 251 K. The temperature dependence of the Landau coefficients have been derived by fitting the magnetization with the Landau expansion of the magnetic free energy, indicating the first-order nature of the magnetic transition between ferromagnetic and paramagnetic states in the compound. (C) 2009 Elsevier B.V. All rights reserved.

Keyword:

Magnetocaloric effect Mn1.1Fe0.9P0.8Ge0.2 compound First-order magnetic transition Fe2P-type structure

Author Community:

  • [ 1 ] [Yue, M.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 2 ] [Li, Z. Q.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 3 ] [Xu, H.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 4 ] [Liu, D. M.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 5 ] [Zhang, J. X.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 6 ] [Liu, X. B.]McGill Univ, Ctr Phys Mat, Montreal, PQ H3A 2T8, Canada
  • [ 7 ] [Liu, X. B.]McGill Univ, Dept Phys, Montreal, PQ H3A 2T8, Canada

Reprint Author's Address:

  • 岳明

    [Yue, M.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2010

Issue: 1-2

Volume: 493

Page: 22-25

6 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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