By　adopting　the　strategy　of　triblock　copolymer　(Pluronic　P123)　or　cetyltrimethylammonium　bromide　(CTAB)　assisted　hydrothermal　treatment,　we　fabricated　cubic　fluorite-type　Ce0.6Zr0.3Y0.1O2　(CZY)　solid　solution　polycrystallites　with　various　morphologies.　These　materials　were　characterized　by　means　of　techniques　such　as　X-ray　diffraction,　scanning　electron　microscopy,　transmission　electron　microscopy,　selected-area　electron　diffraction,　X-ray　photoelectron　spectroscopy,　thermogravimetry,　laser　Raman,　Fourier-transfer　infrared　spectroscopy,　hydrogen　temperature-programmed　reduction,　and　surface　area　measurements.　It　is　found　that　the　nanorod-like,　microspherical,　microbowknot-like,　and　micro-octahedral　CZY　particles　were　respectively　generated　hydrothermally　with　CTAB　at　120　degrees　C　for　72　h　and　with　P123　at　100,　120,　and　240　degrees　C　for　48　h　after　calcination　at　550　degrees　C　for　3　h.　There　was　a　copresence　of　Ce3+　and　Ce4+　in　the　CZY　samples　that　led　to　the　formation　of　oxygen　vacancies.　We　observed　a　good　correlation　of　low-temperature　reducibility　with　the　morphology　of　the　CZY　samples.　The　reducibility　of　these　nano-　and　micromaterials　at　low　temperatures　(240-550　degrees　C)　enhanced　in　the　order　micro-octahedral　CZY　＜　microspherical　CZY　＜　microbowknot-like　CZY　＜　nanorod-like　CZY.　The　formation　mechanism　of　CZY　with　various　morphologies　was　discussed.