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Author:

Zhou Shen-Lin (Zhou Shen-Lin.) | Liu Dan-Min (Liu Dan-Min.) (Scholars:刘丹敏) | Zhang Jin-Xing (Zhang Jin-Xing.)

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

La-LaH2 nanopowders were prepared by hydrogen are plasma method, and then the mixed nanopowders of La-LaH2 and B were in situ sintered by Sparkle Plasma Sintering (SPS) method in oxygen free system. High-purity LaB6 polycrystal nonostructured bulk was successfully synthesized by SPS. The dehydrogenation of LaH2 nanopowders and the reaction equation of sintering LaB6 were studied. The phase and microstructure of LaB6 bulks were characterized by using XRD, SEM, TEM and AFM techniques. The results show that the dehydrogenation temperature of LaH2 nonopowders is 796.4 degrees C. The sintered body is single-phase LaB6, which has a high purity of 99.867%, and its relative densities is up to 99.2%. The hardness and bend strength of the sintered LaB6 are much better than those of LaB6 prepared by other sintering methods. The crystals of LaB6 Bulk are equiaxed crystals, the average grain size of the bulks sintered at 50MPs and 1250-1350 degrees C is about 120nm. The grains are homogenous and integrated, and the grain size increases with the raising of sintering temperature.

Keyword:

hot cathode polycrystal Lanthanum hexaboride spark plasma sintering (SPS) nanostructured bulk

Author Community:

  • [ 1 ] [Zhou Shen-Lin]Beijing Univ Technol, Coll Mat Sci & Engn, Minist Educ, Key Lab Advanced Funct Mat, Beijing 100022, Peoples R China
  • [ 2 ] [Liu Dan-Min]Beijing Univ Technol, Coll Mat Sci & Engn, Minist Educ, Key Lab Advanced Funct Mat, Beijing 100022, Peoples R China
  • [ 3 ] [Zhang Jin-Xing]Beijing Univ Technol, Coll Mat Sci & Engn, Minist Educ, Key Lab Advanced Funct Mat, Beijing 100022, Peoples R China

Reprint Author's Address:

  • [Zhou Shen-Lin]Beijing Univ Technol, Coll Mat Sci & Engn, Minist Educ, Key Lab Advanced Funct Mat, Beijing 100022, Peoples R China

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Source :

JOURNAL OF INORGANIC MATERIALS

ISSN: 1000-324X

Year: 2008

Issue: 6

Volume: 23

Page: 1199-1204

1 . 7 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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