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Author:

Xie, YB (Xie, YB.) (Scholars:谢亚勃) | Li, JR (Li, JR.) (Scholars:李建荣) | Bu, XH (Bu, XH.)

Indexed by:

Scopus SCIE

Abstract:

In our continuous efforts to investigate the coordination architectures of silver(I) complexes with thioethers, we report herein the syntheses and crystal structures of three new silver(I) complexes, a trinuclear complex [Ag3L22(NO3)(2)](NO3)(CH3CN) 2 and two one-dimensional chain complexes [Ag2L1 (BF4)(2)(CH3CN)(2)](infinity) 1 and [Ag2L3 (NO3)(2)](infinity) 3, where L-1, L-2 and L-3 are three structurally related pyridyl dithioether ligands: 1,4-bis(2-pyridylthio)butane (L-1), 1,5-bis(2-pyridylthio)pentane (L-2) and 1,6-bis(2-pyridylthio)hexane (L-3). The structural differences of 1, 2 and 3 show the influences of the ligand spacers on the coordination modes of the terminal pyridylsulfanyl groups and the coordination geometries of the Ag-I ion. There exist (AgAg)-Ag-... contacts in the three complexes, C-(HF)-F-... weak hydrogen bonds in 1, (AgS)-S-... weak coordination bonds in 2 and (AgO)-O-... weak interactions in 2 and 3, and these weak interactions link the low-dimensional complexes into high-dimensional supramolecular structures and further stabilize the crystal structures in the solid states. (C) 2005 Elsevier Ltd. All rights reserved.

Keyword:

crystal structure self-assembly pyridyl dithioether silver(I) complexes weak interactions

Author Community:

  • [ 1 ] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
  • [ 2 ] Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100022, Peoples R China

Reprint Author's Address:

  • [Bu, XH]Nankai Univ, Dept Chem, 94 Weijin Rd, Tianjin 300071, Peoples R China

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Source :

POLYHEDRON

ISSN: 0277-5387

Year: 2005

Issue: 3

Volume: 24

Page: 413-418

2 . 6 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 26

SCOPUS Cited Count: 26

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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