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Author:

Zhang, Wenjie (Zhang, Wenjie.) | Qi, Yanfei (Qi, Yanfei.) | Zhang, Lixia (Zhang, Lixia.) | Tang, Yunhui (Tang, Yunhui.) | Qi, Chao (Qi, Chao.) | Shen, Qi (Shen, Qi.) | Ma, Yutian (Ma, Yutian.) | Wang, Bo (Wang, Bo.) (Scholars:王波)

Indexed by:

EI Scopus SCIE

Abstract:

Tungsten is considered as the foremost candidate material for the plasma facing material (PFM) in future fusion device, and excellent high temperature oxidation resistance is the important safety criterion to prevent radioactive pollution in case of a Loss-of-Coolant-Accident (LOCA) with simultaneous air ingress. Recently, high entropy alloys were found to have prominent high temperature oxidation resistance and corrosion resistance. The present paper focuses on the high temperature oxidation resistance of tungsten based high entropy alloy, and their structures and corrosion resistances are also studied. In this study, thin films of W, WTa, WTaCr, WTaCrV, WTaCrVAl, WTaCrVAlTi and WTaCrVAlTiZr were prepared via the magnetron sputtering method with a kind of composed target consisting of fan-shapes. The results show that as the number of selected elements increases, the entropy increases, the disorder of film structure increases significantly resulting in the formation of amorphous structure, and the corrosion resistance and oxidation resistance of the alloys also improve greatly. The further analysis and experiments proved that: one important reason for the improving of corrosion resistance and oxidation resistance is that the increase of mixing entropy reduces the Gibbs free energy of alloys and makes them more chemically stable; another reason is that the elements of Cr, Al, Ti and Zr can promote the formation of dense oxide passive layer.

Keyword:

Oxidation kinetics Corrosion behavior Microstructure Tungsten alloys High entropy alloy

Author Community:

  • [ 1 ] [Zhang, Wenjie]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Property Adv Mat, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China
  • [ 2 ] [Tang, Yunhui]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Property Adv Mat, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China
  • [ 3 ] [Qi, Chao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Property Adv Mat, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China
  • [ 4 ] [Shen, Qi]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Property Adv Mat, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Bo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Property Adv Mat, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China
  • [ 6 ] [Qi, Yanfei]North China Univ Sci & Technol, Tangshan 063210, Peoples R China
  • [ 7 ] [Zhang, Lixia]HangTianKeGong Grp, Def Technol Res & Test Ctr, Beijing 100854, Peoples R China
  • [ 8 ] [Ma, Yutian]Chinese Acad Sci, Inst Elect Engn, Beijing 100190, Peoples R China

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Source :

SURFACE & COATINGS TECHNOLOGY

ISSN: 0257-8972

Year: 2022

Volume: 434

5 . 4

JCR@2022

5 . 4 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 20

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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