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Author:

Song, Ziwen (Song, Ziwen.) | Zhang, Zhuo (Zhang, Zhuo.) | Luo, Canyu (Luo, Canyu.) | Yang, Likun (Yang, Likun.) | Wu, Jin (Wu, Jin.)

Indexed by:

Scopus SCIE

Abstract:

Phosphate rock powder (PR) has been shown to possess the potential to stabilize lead (Pb) in soil. Most of the phosphorus (P) minerals in the world are low-grade ores, making it difficult to achieve the expected stabilization effect on heavy metals. This study compared the changes in the phase composition and structure of PR and three kinds of activated phosphate rock powder (APR) (organic acid-activated PR, thermal-activated PR, and thermal-organic acid-activated PR). The stabilization effectiveness of APR on Pb-contaminated soil was evaluated by toxicity leaching procedure; the Pb products adsorbed on APR and stabilization mechanism of APR on Pb were analyzed. The results demonstrated that APR showed decreased crystallinity and 3.4-fold increase in specific surface area, and a 53.07% and 49.32% increase in soluble P content in oxalic acid-activated PR and citric acid-activated PR, respectively, when compared with those of PR. These changes improved the stabilization effect of APR on Pb-contaminated soil, in which oxalic acid-600 degrees C-activated PR showed the best effect, presenting 94.0-99.8% reduction in Pb leaching concentration following addition of 2-10% modifier. Product characterization after Pb adsorption on APR showed that Pb was adsorbed onto APR by forming fluoropyromophite precipitation with APR.

Keyword:

Stabilization Lead-contaminated soil Thermal-organic acid activation Phosphate rock powder

Author Community:

  • [ 1 ] [Song, Ziwen]China Univ Geosci, Sch Land Sci & Technol, Beijing 100083, Peoples R China
  • [ 2 ] [Zhang, Zhuo]China Univ Geosci, Sch Land Sci & Technol, Beijing 100083, Peoples R China
  • [ 3 ] [Luo, Canyu]China Univ Geosci, Sch Land Sci & Technol, Beijing 100083, Peoples R China
  • [ 4 ] [Yang, Likun]China Univ Geosci, Sch Land Sci & Technol, Beijing 100083, Peoples R China
  • [ 5 ] [Song, Ziwen]Minist Nat Resources, Key Lab Land Consolidat & Rehabil, Beijing 100035, Peoples R China
  • [ 6 ] [Zhang, Zhuo]Minist Nat Resources, Key Lab Land Consolidat & Rehabil, Beijing 100035, Peoples R China
  • [ 7 ] [Wu, Jin]Beijing Univ Technol, Coll Architecture & Civil Engn, Beijing 100124, Peoples R China

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Source :

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH

ISSN: 0944-1344

Year: 2022

Issue: 32

Volume: 29

Page: 49116-49125

5 . 8

JCR@2022

5 . 8 0 0

JCR@2022

ESI Discipline: ENVIRONMENT/ECOLOGY;

ESI HC Threshold:47

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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