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Author:

Qi, Lei (Qi, Lei.) | Li, Ang (Li, Ang.) | Wang, Mei (Wang, Mei.) | Zhang, Yin (Zhang, Yin.) | Zhang, Kai (Zhang, Kai.) | Li, Xinheng (Li, Xinheng.)

Indexed by:

EI Scopus SCIE

Abstract:

Electrolysis of seawater will alleviate strain on fresh water scarcity. Non-noble metal compounds as substitutes for precious metals for oxygen evolution reaction (OER) have been intensively studied. However, to make OER electrocatalyst efficient and stable in seawater is still an issue to be solved. In view of this, an attempt to fabricate nickel foam (NF)-enclosed reduced graphene oxide (rGO) supported sub-nanometer arrays of NiFe phosphide is reported. The as-obtained NiFeP/P-doped rGO/NF (NiFeP/P-rGO/NF) at current densities of 100 and 400 mA cm(-2) shows overpotentials of 290 and 340 mV respectively, well below 490 mV overpotential that avoided triggering chloride oxidation in seawater (1 m KOH+1 m NaCl). The Tafel slope of NiFeP/P-rGO/NF is as low as 71.9 mV dec(-1). Moreover, no considerable loss of current density is observed after 450 h at 35 mA cm(-2). This strategy is extended to fabricate CoFeP/P-rGO/NF and IrO2/rGO/NF and they also show superior activity. The combination of ultrathin NiFeP arrays and conductive network of rGO are the key to superior activity. Hydrophobicity of the rGO is accountable for good durability in seawater.

Keyword:

reduced graphene oxide transition metal phosphide nickel foam electrolysis of seawater oxygen evolution reaction

Author Community:

  • [ 1 ] [Qi, Lei]Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
  • [ 2 ] [Wang, Mei]Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
  • [ 3 ] [Zhang, Yin]Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
  • [ 4 ] [Li, Xinheng]Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
  • [ 5 ] [Qi, Lei]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 6 ] [Wang, Mei]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 7 ] [Li, Ang]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Pingleyuan 100, Beijing 100124, Peoples R China
  • [ 8 ] [Zhang, Kai]Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China

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Source :

ADVANCED MATERIALS INTERFACES

ISSN: 2196-7350

Year: 2021

Issue: 2

Volume: 9

5 . 4 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:116

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 17

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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