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Author:

Liu, Yue (Liu, Yue.) | Li, Xuejian (Li, Xuejian.) | Liu, Tongtong (Liu, Tongtong.) | Zheng, Zilong (Zheng, Zilong.) | Liu, Qiaohong (Liu, Qiaohong.) | Wang, Yan (Wang, Yan.) | Qin, Zhenping (Qin, Zhenping.) | Guo, Hongxia (Guo, Hongxia.) (Scholars:郭红霞) | Liang, Yucang (Liang, Yucang.)

Indexed by:

EI Scopus SCIE

Abstract:

Molybdenum disulfide-based membranes have received wide attention for their excellent performance in chemical separation field. Yet, manipulating the structure of MoS2 membranes still remains an unprecedented challenge. In this work, the tubular MoS2 ceramic membranes were prepared by in-situ hydrothermal method using aqueous solution of thiourea and ammonium molybdate as precursor solution. The structure and morphology of the membranes were manipulated by introducing different alcohols into the precursor solution. The results indicated that the presence of alcohols drove the transformation of MoS2 morphology from nano sheets to spherical aggregates. As the molecular weight of the alcohols decreased, more small-sized molybdenum disulfide spheres were formed on the tubular ceramic substrate, which resulted in the formation of a great number of large transportation channels and promotion of surface area, and thereby improved the permeability of the membrane. Moreover, the addition of different alcohols enhanced the negative charge of the membrane surface, which ensured an effective rejection while enhancing the membrane permeability. The results demonstrate that the membranes prepared in a water-ethanol mixed solvent possess an excellent permeability for water (33.2 L/(m(2) h bar)) and methanol (52.2 L/(m(2) h bar)), with a rejection of more than 97% for Eriochrome black T, and an excellent pressure resistance as well as long-term running stability under cross-flow filtration. In addition, such membrane exhibited a below 30% rejection for salts, which can be utilized for dye desalination.

Keyword:

In-situ hydrothermal method Nanofiltration Alcohols MoS2 ceramic membrane Dye desalination

Author Community:

  • [ 1 ] [Liu, Yue]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Xuejian]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Zheng, Zilong]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Guo, Hongxia]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Tongtong]Beijing Univ Technol, Coll Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Qiaohong]Beijing Univ Technol, Coll Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 7 ] [Wang, Yan]Beijing Univ Technol, Coll Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 8 ] [Qin, Zhenping]Beijing Univ Technol, Coll Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 9 ] [Liang, Yucang]Eberhard Karls Univ Tubingen, Inst Anorgan Chem, Morgenstelle 18, D-72076 Tubingen, Germany

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Source :

JOURNAL OF MEMBRANE SCIENCE

ISSN: 0376-7388

Year: 2022

Volume: 659

9 . 5

JCR@2022

9 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:53

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 9

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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