To　improve　the　thermal　properties　of　aluminum(Al)in　the　energetic　system,a　coated　structure　with　ammonium　perchlorate(AP)was　prepared　by　a　facile　approach.And　N,N-Dimethylformamide(DMF)was　chosen　as　an　ideal　solvent　based　on　heterogeneous　nucleation　theory　and　molecular　dynamics　simulation.This　coated　structure　could　enlarge　the　contact　area　and　improve　the　reaction　environment　to　enhance　the　thermal　properties.The　addition　of　AP　could　accelerate　oxidation　temperature　of　Al　with　around　17.5℃.And　the　heat　release　of　85@15　composition　rises　to　26.13　kJ/g　and　the　reaction　degree　is　97.6％with　higher　peak　pressure(254.6　kPa)and　rise　rate(1.397　MPa/s).An　ideal　ratio　with　15　wt％AP　was　probed　primarily.The　high　energy　laser-induced　shockwave　experiment　was　utilized　to　simulate　the　reaction　behavior　in　hot　field.And　the　larger　activated　mixture　of　coated　powder　could　release　more　energy　to　promote　the　growth　of　shockwave　with　higher　speed　up　to　518.7±55.9　m/s.In　conclusion,85@15　composition　is　expected　to　be　applied　in　energetic　system　as　a　novel　metal　fuel.