A　series　of　multiblock　sulfonated　poly(arylene　ether　sulfone)s(SPAES)with　various　block　lengths　and　predictable　ion　exchange　capacity　were　synthesized　from　4,4＇-difluorodiphenyl　sulfone,4,4＇-dihydrodiphenyl　sulfone　and　4,4＇-biphenol　by　one-pot　and　two-pot　polymerization.1H-NMR　and　FTIR　spectra　confirmed　the　structure　that　sulfonic　acid　groups　were　introduced　precisely　on　the　poly(arylene　ether　sulfone)s　by　post-sulfonation　which　resulted　in　controllable　sulfonation　degree.The　proton　exchange　membranes(PEMs)-based　SPAES　displayed　excellent　dimensional,thermal,antioxidant　stability,proton　conductivity　and　mechanical　properties(maximum　tensile　stress＞35　MPa).Thermogravimetric　analysis　indicated　the　prepared　SPAES　began　to　degrade　above　310℃.The　effects　of　polymerization　processes,those　were,one-pot　hydrophobic　segment　process,one-pot　hydrophilic　segment　process　and　two-pot　process,on　the　properties　of　polymers　were　investigated.The　proton　conductivity　and　microphase　separation　of　SPAES　PEMs　increased　in　order　of　those　prepared　by　one-pot　hydrophobic　segment　process,two-pot　process　and　one-pot　hydrophilic　segment　process.The　highest　conductivities　of　SPAES　synthesized　by　the　above　processes　under　80℃and　100％relative　humidity　were　213(MS4),297(MB3)and　360　mS·cm-1(MQ2),respectively.