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Author:

Zhao, Chen (Zhao, Chen.) | Li, Yi (Li, Yi.) | Xiao, Jin-Sheng (Xiao, Jin-Sheng.) | Zhang, Peng-Dan (Zhang, Peng-Dan.) | Wu, Xue-Qian (Wu, Xue-Qian.) | Chen, Qiang (Chen, Qiang.)

Indexed by:

Scopus

Abstract:

The asymmetric unit of the title coordination polymer, [Co(C9H4N2O4)(C2H4N4)(n) or [Co(L-1)(L-2)](n) consists of one crystallographically independent Co2+ centre, one L-1(2-) ligand and one L-2 ligand (L-1 = 1H-benzimidazole-5,6-dicarboxylic acid, L-2 = 3-amino-1,2,4-triazole). The Co2+ centre is coordinated by two carboxylato-O atoms from two independent L-1(2-) ligands and two nitrogen atoms from L-2 and another L-1 ligand. Thus, the metal center adopts a four-coordinate mode, forming a tetrahedral geometry. Interestingly, through the combination of two L-1(2-), two L-2 ligands and two Co2+ ions, a basic repeating unit is constructed, resulting in the formation of a one-dimensional straight chain structure. These chains are further expanded to the final three-dimensional framework via N-H center dot center dot center dot O hydrogen-bonding interactions.

Keyword:

crystal structure coordination polymer dicarboxylic acid mixed-ligands synthetic strategy imidazole

Author Community:

  • [ 1 ] [Wu, Xue-Qian]Beijing Univ Technol, Fac Environm & Life, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Wu, Xue-Qian]Beijing Univ Technol, Fac Environm & Life, Dept Environm Chem Engn, Beijing 100124, Peoples R China

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Source :

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

ISSN: 2056-9890

Year: 2021

Volume: 77

Page: 714-,

0 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:96

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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