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Abstract:
The asymmetric unit of the title coordination polymer, [Co(C9H4N2O4)(C2H4N4)(n) or [Co(L-1)(L-2)](n) consists of one crystallographically independent Co2+ centre, one L-1(2-) ligand and one L-2 ligand (L-1 = 1H-benzimidazole-5,6-dicarboxylic acid, L-2 = 3-amino-1,2,4-triazole). The Co2+ centre is coordinated by two carboxylato-O atoms from two independent L-1(2-) ligands and two nitrogen atoms from L-2 and another L-1 ligand. Thus, the metal center adopts a four-coordinate mode, forming a tetrahedral geometry. Interestingly, through the combination of two L-1(2-), two L-2 ligands and two Co2+ ions, a basic repeating unit is constructed, resulting in the formation of a one-dimensional straight chain structure. These chains are further expanded to the final three-dimensional framework via N-H center dot center dot center dot O hydrogen-bonding interactions.
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Source :
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
ISSN: 2056-9890
Year: 2021
Volume: 77
Page: 714-,
0 . 9 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
ESI HC Threshold:96
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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