Zinc-air　batteries　(ZABs)　are　regarded　as　attractive　devices　for　electrochemical　energy　storage　and　conversion　due　to　their　outstanding　electrochemical　performance,　low　price,　and　high　safety.　However,　it　remains　a　chal-lenge　to　design　a　stable　and　efficient　bifunctional　oxygen　catalyst　that　can　accelerate　the　reaction　kinetics　and　improve　the　performance　of　ZABs.　Herein,　a　phosphorus-doped　transition　metal　selenide/carbon　com-posite　catalyst　derived　from　metal-organic　frameworks　(P-CoSe2/C@CC)　is　constructed　by　a　self-supporting　carbon　cloth　structure　through　a　simple　solvothermal　process　with　subsequent　selenization　and　phosphati-zation.　The　P-CoSe2/C@CC　exhibits　a　low　overpotential　of　303.1　mV　at　10　mA　cm-2　toward　the　oxygen　evo-lution　reaction　and　an　obvious　reduction　peak　for　the　oxygen　reduction　reaction.　The　abovementioned　electrochemical　performances　for　the　P-CoSe2/C@CC　are　attributed　to　the　specific　architecture,　the　super-hydrophilic　surface,　and　the　P-doping　effect.　Remarkably,　the　homemade　zinc-air　battery　based　on　our　P-CoSe2/C@CC　catalyst　shows　an　expected　peak　power　density　of　124.4　mW　cm-2　along　with　excellent　cycling　stability,　confirming　its　great　potential　application　in　ZABs　for　advanced　bifunctional　electrocatalysis.(c)　2022　Elsevier　Inc.　All　rights　reserved.