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Abstract:
Nanocomposite permanent magnets have ultra-high theoretical magnetic energy products, due to cou-pling of the soft/hard magnetic phases, inciting strict microstructural requirements. In this study, the microstructure evolution, including the phase transition, morphological changes, and texture formation, of hot-deformed SmCo-based nanocomposites under thermal-stress-strain coupling was characterized to determine a possible strategy for achieving high performance. The SmCo5/alpha-Fe nanocomposites precursor contained fine and dispersed Sm(Fe, Co)5 and Fe-Co grains and exhibited a two-stage phase transforma-tion accompanied by grain growth. In the early stage of deformation at relatively low temperature, the adjacent Sm(Co, Fe)5 and Fe-Co phase formed the Sm2(Co, Fe)17-H phase, which was stable only with small grain sizes. In the high-temperature deformation stage, the Sm2(Co, Fe)17-H phase transformed into the Sm2(Co, Fe)17-R phase with large grain sizes. In addition, the strong c-axis texture formed in the Sm(Co, Fe)5 phase but not in the Sm2(Co, Fe)17-R phase. Subsequently, the phase transition process and texture formation mechanism were systematically analyzed by transmission electron microscopy. The ini-tiation of a slip system and/or preferential grain growth explained the formation of texture under the action of uniform stress and strain and assisted by dispersed Sm-rich nanograins. The Sm2(Co, Fe)17-R grains with poor orientations and large grain sizes did not achieve magnetic hardening, which also dam-age the magnetic properties. According to the results of this work, we also presented a new strategy to prepare high-performance SmCo-based nanocomposites magnets.(c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN: 1005-0302
Year: 2023
Volume: 138
Page: 193-202
1 0 . 9 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:26
Cited Count:
WoS CC Cited Count: 11
SCOPUS Cited Count: 13
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 6
Affiliated Colleges: