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Author:

Zhou, Xiaozhong (Zhou, Xiaozhong.) | Qi, Zhaoyi (Qi, Zhaoyi.) | Jiang, Yuyuan (Jiang, Yuyuan.) | Yan, Pengfei (Yan, Pengfei.) | Ding, Juanxia (Ding, Juanxia.) | Wang, Haiyan (Wang, Haiyan.) | Lu, Hongkai (Lu, Hongkai.) | Liu, Dongxu (Liu, Dongxu.) | Dong, Kaifa (Dong, Kaifa.) | Tang, Yougen (Tang, Yougen.) | Sun, Dongfei (Sun, Dongfei.) | Lei, Ziqiang (Lei, Ziqiang.)

Indexed by:

EI Scopus SCIE

Abstract:

SiOx is regarded as a promising anode material for the next-generation lithium-ion batteries with high energy density. However, the reduplicative volume changes during cycling cause the pulverizations of Si, leading to decreased utilization of active Si component and poor cycling performance. Herein, a facile and scalable Fe-Cr decorating strategy is reported to boost the lithium storage of SiOx anode. Our comprehensive characterizations indicate that there are strong interactions between Fe-Cr and SiOx during a facile ball milling process. After cycling, Fe-Cr nanoparticles are dispersed in the in-situ formed lithium silicates and Li2O matrix, which can maintain superior conductivity of lithium ion and electron for the active components through point-to-point connections. This unique structure boosts the electrochemical de-alloying process of the low-valent LixSi (0 <= x <= 2), and increases effective utilization of the active Si component during cycling, resulting in improvement of reversible capacity and cycling stability. This bm SiOx-FeCr electrode can deliver high reversible specific capacity (1370 m Ah g (-1) at 200 mA g(-1)), good rate capability (653.8 m Ah g(-1) at 20 0 0 mA g(-1)), and superior cycling stability. This work provides a promising route for improving the utilization of active Si component and the structural stability of SiOx-based anodes. (c) 2021 Elsevier Ltd. All rights reserved.

Keyword:

SiOx -based anode Cycling stability Boosting de-lithiation Fe-Cr alloy Lithium-ion batteries

Author Community:

  • [ 1 ] [Zhou, Xiaozhong]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 2 ] [Qi, Zhaoyi]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 3 ] [Ding, Juanxia]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 4 ] [Lu, Hongkai]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 5 ] [Liu, Dongxu]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 6 ] [Dong, Kaifa]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 7 ] [Sun, Dongfei]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 8 ] [Lei, Ziqiang]Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Key Lab Ecoenvironm Polymer Mat Gansu Prov,Minist, Lanzhou, Peoples R China
  • [ 9 ] [Zhou, Xiaozhong]Cent South Univ, Coll Chem & Chem Engn, Changsha, Peoples R China
  • [ 10 ] [Wang, Haiyan]Cent South Univ, Coll Chem & Chem Engn, Changsha, Peoples R China
  • [ 11 ] [Tang, Yougen]Cent South Univ, Coll Chem & Chem Engn, Changsha, Peoples R China
  • [ 12 ] [Jiang, Yuyuan]Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen Geim Graphene Ctr, Shenzhen, Peoples R China
  • [ 13 ] [Jiang, Yuyuan]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Property Solids, Beijing, Peoples R China
  • [ 14 ] [Jiang, Yuyuan]Tsinghua Univ, Inst Mat Res, Tsinghua Shenzhen Int Grad Sch, Shenzhen, Peoples R China

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Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2022

Volume: 406

6 . 6

JCR@2022

6 . 6 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:53

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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