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Abstract:
The growing demand of advanced electrochemical energy storage devices for various applications, including portable electronic products, electric vehicles, and large-scale energy storage grids, hastriggered extensive research interests and efforts on various rechargeable batteries such as lithium/sodium-ion batteries (LIBs/NIBs), aluminium-ion batteries (AIBs), liquid metal batteries (LMBs), andmolten-air batteries (MABs) in the past decades. A key issue to push forward the development of thesebatteries is the exploration of high-performance electrodes and electrolytes, which calls for efficientand versatile synthetic methods. Molten salts (MSs), liquid-phase ionic compounds or mixtures,provide an effective platform to widen the reaction temperatures and enrich the chemical environ-ments for the synthesis of novel electrode materials and electrolytes. In this review, the generalprinciples of molten salts and recent research progresses on molten salt-based battery materials aresurveyed. Molten-salt synthesis of electrode materials, including sintering and electrolysis, areemerging as competitive substitutes for conventional synthesis techniques. These methods haveshown their effectiveness and uniqueness in adjusting the crystal structure, morphology, andperformance of electrode materials for LIBs/NIBs, as suggested by recent progresses and applicationsof diverse cathodes (layered oxides, spinel oxides, polyanions, etc.) and anodes (metal oxides, alloys,carbons, etc.). Furthermore, the applications of molten salts as effective electrolytes are demonstratedin representative new-type secondary batteries including AIBs, LMBs and MABs. Finally, the emergingopportunities, challenges, and interesting research trends are envisioned to promote the further development of molten-salt methodology for rechargeable batteries
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MATERIALS TODAY
ISSN: 1369-7021
Year: 2022
Volume: 60
Page: 128-157
2 4 . 2
JCR@2022
2 4 . 2 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:66
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 37
SCOPUS Cited Count: 41
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 7
Affiliated Colleges: