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Author:

Liu, J. (Liu, J..) | Chang, L. (Chang, L..) | Wang, R. (Wang, R..)

Indexed by:

EI Scopus

Abstract:

In order to explore the synthesis of new type of low platinum catalyst for proton exchange membrane fuel cells with high catalytic activity and stability, a phosphorus-doped modified carbon-supported platinum catalyst (Px-Pt/C) was successfully prepared by an improved impregnation reduction method. The electrochemical performance test proves that the catalytic oxygen reduction reaction (ORR) performance of Pt/C can be improved by phosphorus doping. The mass activity (MA) of P1.5-Pt/C is 1.6 times higher than that of JM20Pt/C. After 10 000 cycles accelerated durability test, the electrochemical surface area (ECSA) of P1.5-Pt/C increases by 2.92%, with MA decreasing by 43.87%, while the ECSA of JM20Pt/C decreases by 33.7%, with MA decreasing by 53.33%, respectively. It is shown that phosphating can improve the ORR catalytic activity and stability of Pt/C catalysts. © 2022 Cailiao Daobaoshe/ Materials Review. All rights reserved.

Keyword:

stability phosphorus doping oxygen reduction reaction platinum-based catalyst proton exchange membrane fuel cell

Author Community:

  • [ 1 ] [Liu J.]Key Laboratory of Advanced Functional Materials of Education, Ministry of China, Institute of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Chang L.]Key Laboratory of Advanced Functional Materials of Education, Ministry of China, Institute of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Wang R.]Key Laboratory of Advanced Functional Materials of Education, Ministry of China, Institute of Advanced Energy Materials and Devices, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China

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Source :

Materials Reports

ISSN: 1005-023X

Year: 2022

Issue: 21

Volume: 36

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 12

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