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Abstract:
In order to explore the synthesis of new type of low platinum catalyst for proton exchange membrane fuel cells with high catalytic activity and stability, a phosphorus-doped modified carbon-supported platinum catalyst (Px-Pt/C) was successfully prepared by an improved impregnation reduction method. The electrochemical performance test proves that the catalytic oxygen reduction reaction (ORR) performance of Pt/C can be improved by phosphorus doping. The mass activity (MA) of P1.5-Pt/C is 1.6 times higher than that of JM20Pt/C. After 10 000 cycles accelerated durability test, the electrochemical surface area (ECSA) of P1.5-Pt/C increases by 2.92%, with MA decreasing by 43.87%, while the ECSA of JM20Pt/C decreases by 33.7%, with MA decreasing by 53.33%, respectively. It is shown that phosphating can improve the ORR catalytic activity and stability of Pt/C catalysts. © 2022 Cailiao Daobaoshe/ Materials Review. All rights reserved.
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Materials Reports
ISSN: 1005-023X
Year: 2022
Issue: 21
Volume: 36
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 12
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