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Author:

Su, Xueqiong (Su, Xueqiong.) | Chen, Ruixiang (Chen, Ruixiang.) | Pan, Yong (Pan, Yong.) | Wang, Jin (Wang, Jin.) | Gao, Dongwen (Gao, Dongwen.) | Yu, Huimin (Yu, Huimin.) | Wang, Yimeng (Wang, Yimeng.) | Wang, Li (Wang, Li.)

Indexed by:

EI Scopus SCIE

Abstract:

An effective method to improve optical properties of perovskite CsPbI3/Br3 is a long-term goal pursued by re-searchers, such as incorporating, mechanism changing and structure optimizing. However, two significant problems still facing challenges including the complex fabrication process and low modulation efficiency. To contribute these, a method of ionic liquid modulation with respect to the photoluminescence PL intensity and peak position was demonstrated. The micro-structure including the information of crystal and bond in MAPbBr3/ I3 soaking in C8H11F3N2O2 and C7H13N2 center dot BF4 was supported by x-ray diffraction XRD patterns and Raman spectrum. A cube-like shape and size distribution mostly in 600-950 nm was imaged by scanning electron mi-croscope. Then, compared with CsPbI3 before soaking in Hall measurement, the carrier concentration was improved about 46.1%, the mobility and resistivity were lowered around 39.2% and 40.2%, respectively. The modulation of intensity and peak position were confirmed by PL spectrum at room temperature. The absorption enhancement in excited state absorbs range was proved by transient absorption. Finally, the mechanism for optical modulation in this paper was systematically explained. The research method proposed in this paper can simplify the research process and improve the optical properties of the materials at the same time.

Keyword:

Modulation Perovskite Ionic liquid TAS

Author Community:

  • [ 1 ] [Su, Xueqiong]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Chen, Ruixiang]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Jin]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Gao, Dongwen]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Yu, Huimin]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Li]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 7 ] [Pan, Yong]Xian Univ Architecture & Technol, Coll Sci, Xian 710055, Peoples R China
  • [ 8 ] [Wang, Yimeng]Univ Shanghai Sci & Technol, Sch Opt Elect & Comp Engn, Shanghai 200093, Peoples R China

Reprint Author's Address:

  • [Su, Xueqiong]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China;;[Wang, Li]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China;;

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Source :

OPTICAL MATERIALS

ISSN: 0925-3467

Year: 2022

Volume: 136

3 . 9

JCR@2022

3 . 9 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:66

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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