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Author:

Lu, Q. (Lu, Q..) | Shao, Y. (Shao, Y..) | Yin, Y. (Yin, Y..) | Chen, H. (Chen, H..) | Xu, H. (Xu, H..) | Liu, W. (Liu, W..) | Liu, M. (Liu, M..) | Zhong, C. (Zhong, C..) | Yu, X. (Yu, X..) | Chen, J. (Chen, J..) | Liu, Y. (Liu, Y..) | Yi, X. (Yi, X..) | Yue, M. (Yue, M..)

Indexed by:

EI Scopus SCIE

Abstract:

Machined sintered NdFeB (S-NdFeB) wastes typically contain about 30 wt% rare earth (RE) elements which are beneficial as supplemental RE resources. In this work, we studied one type of oily and adhesive-containing scraps, and developed a high-value recycling technique based on surface treatments-RE manipulation-grain boundary diffusion, specifically to directly generate multi-grade, high-performance S-NdFeB magnets. We obtained clean-surface scraps with RE mass loss of less than 4% and oxygen content below 2000 ppm using a custom-made solvent. By increasing content of the RE-rich alloy (Nd4Fe14B), we quickly improved the performance of the regenerated magnets. When the addition was 15 wt%, the magnetic properties exceeded that of the original magnet, with a remanence of 12.5 kG, coercivity of 17.79 kOe, and maximum energy product of 37.95 MGOe. Furthermore, the magnets were subjected to 1 wt% TbHx-diffusion treatment, which further optimized the performance, and the coercivity exhibited a 50% improvement to 26.71 kOe, which greatly expanded the application in motors and generators. Microstructure analysis indicated that the improved magnetic performance of the regenerated magnets was mainly derived from the restoration of the RE-rich phase, and the Nd2Fe14B-(Nd/Tb)2Fe14B core-shell structure, which had a high anisotropic field. Based on the above recycling methods, we successfully established an energy conservation and efficient recycling line for S-NdFeB wastes at a scale of five hundred tons/year. © 2023

Keyword:

Grain boundary diffusion RE manipulation Regeneration Machined S-NdFeB scrap Surface treatment

Author Community:

  • [ 1 ] [Lu Q.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Lu Q.]Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing, 100124, China
  • [ 3 ] [Shao Y.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Yin Y.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Chen H.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Xu H.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 7 ] [Liu W.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 8 ] [Liu W.]Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing, 100124, China
  • [ 9 ] [Liu M.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 10 ] [Liu M.]Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing, 100124, China
  • [ 11 ] [Zhong C.]Ganzhou Fortune Electronic Co. Ltd., Ganzhou, 341000, China
  • [ 12 ] [Yu X.]Ganzhou Fortune Electronic Co. Ltd., Ganzhou, 341000, China
  • [ 13 ] [Chen J.]Earth-Panda Advanced Magnetic Materials Co. Ltd., Hefei, 231500, China
  • [ 14 ] [Liu Y.]Earth-Panda Advanced Magnetic Materials Co. Ltd., Hefei, 231500, China
  • [ 15 ] [Yi X.]Earth-Panda Advanced Magnetic Materials Co. Ltd., Hefei, 231500, China
  • [ 16 ] [Yue M.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 17 ] [Yue M.]Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing, 100124, China

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Source :

Sustainable Materials and Technologies

ISSN: 2214-9937

Year: 2023

Volume: 36

9 . 6 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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