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Author:

Gao, Qi (Gao, Qi.) | Han, Shuai (Han, Shuai.) | Ye, Qing (Ye, Qing.) (Scholars:叶青) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (Scholars:程水源) | Kang, Tianfang (Kang, Tianfang.) (Scholars:康天放) | Dai, Hongxing (Dai, Hongxing.) (Scholars:戴洪兴)

Indexed by:

Scopus SCIE

Abstract:

Lanthanide (La, Ce, Nd, Gd, Tb, Ho or Lu)-doped Cu-SAPO-18 samples were prepared using the ion-exchange method. Physicochemical properties of the samples were systematically characterized by a number of analytical techniques, and the effects of lanthanide doping on catalytic activity and hydrothermal stability of the Cu-SAPO-18 catalysts for the NH3-SCR reaction were examined. It is shown that the doping of lanthanide elements could affect the interaction between the active components (copper ions) and the AEI-structured SAPO-18 support. The inclusion of some lanthanides significantly slowed down hydrolysis of the catalyst during hydrothermal aging treatment process, leading to an enhanced catalytic activity at both low and high temperatures and hydrothermal stability. In particular, Ce doping promoted the Cu2+ ions to migrate to the energetically favorable sites for enhancement in catalytic activity, whereas the other lanthanide ions exerted little or an opposite effect on the migration of Cu2+ ions. Additionally, Ce doping could improve hydrothermal stability of the Cu-SAPO-18 catalyst by weakening hydrolysis of the catalyst during the hydrothermal aging treatment process. Ce doping increased the catalytic activity of Cu-SAPO-18 at low and high temperatures, which was attributed to modifications of the redox and/or isolated Cu2+ active centers.

Keyword:

NH3-SCR selective catalytic reduction lanthanide doping SAPO-18-incorporated Cu catalyst hydrothermal stability

Author Community:

  • [ 1 ] [Gao, Qi]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Han, Shuai]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Ye, Qing]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Cheng, Shuiyuan]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Kang, Tianfang]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Coll Environm & Energy Engn,Dept Chem & Chem Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 叶青 戴洪兴

    [Ye, Qing]Beijing Univ Technol, Dept Environm Sci, Coll Environm & Energy Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Coll Environm & Energy Engn,Dept Chem & Chem Engn, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Lab Catalysis Chem & Nanosci, Beijing 100124, Peoples R China

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Source :

CATALYSTS

Year: 2020

Issue: 3

Volume: 10

3 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:139

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 18

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

Online/Total:215/10641819
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