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Author:

Li, Y. (Li, Y..) | Zhuang, C. (Zhuang, C..) | Qiu, S. (Qiu, S..) | Gao, J. (Gao, J..) | Zhou, Q. (Zhou, Q..) | Sun, Z. (Sun, Z..) | Kang, Z. (Kang, Z..) | Han, X. (Han, X..)

Indexed by:

EI Scopus SCIE

Abstract:

Metal halide perovskites with broad optical absorption and long carrier lifetime are considered as ideal photocatalysts. However, their poor stability in water greatly impedes their application in photocatalytic H2 evolution because they lose their crystalline structure in water. Herein, we proclaim a new class of photocatalysts: all-inorganic Cs-Cu-Cl perovskite quantum dots (QDs). It exhibits a high photocatalytic hydrogen production rate of ∼ 3.1 mmol/g/h without any cocatalyst under AM 1.5-G solar irradiation (100 mW/cm2). Especially, it remains the high activity for up to 330 h without apparent deterioration of the hydrogen production rate. Density functional theory (DFT) calculations reveal that the Cu site works as the electron and proton absorption sites as the H2 production active center. To our best knowledge, there is no report of metal halide perovskites as water-stable photocatalysts. This work opens an innovative way for guiding the exploration of metal halide perovskites photocatalysts for stable photocatalytic H2 evolution. © 2023 Elsevier B.V.

Keyword:

All-in-one Quantum dot Water-stable Single-component perovskite Photocatalysis

Author Community:

  • [ 1 ] [Li Y.]Institute of Microstructure and Property of Advanced Materials, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Zhuang C.]Institute of Microstructure and Property of Advanced Materials, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Qiu S.]Key Laboratory of Material Modification by Laser, Ion and Electron Beams, School of Physics and DUT-BSU Joint Institute, Dalian University of Technology, Dalian, 116024, China
  • [ 4 ] [Gao J.]Key Laboratory of Material Modification by Laser, Ion and Electron Beams, School of Physics and DUT-BSU Joint Institute, Dalian University of Technology, Dalian, 116024, China
  • [ 5 ] [Zhou Q.]Institute of Microstructure and Property of Advanced Materials, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Sun Z.]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, China
  • [ 7 ] [Kang Z.]Institute of Functional Nano and Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-based Functional Materials and Devices, Soochow University, Suzhou, 215123, China
  • [ 8 ] [Kang Z.]Macao Institute of Materials Science and Engineering (MIMSE), MUST−SUDA Joint Research Center for Advanced Functional Materials, Macau University of Science and Technology, Taipa, 999078, Macao
  • [ 9 ] [Han X.]Institute of Microstructure and Property of Advanced Materials, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2023

Volume: 337

2 2 . 1 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 28

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 20

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