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Author:

Zhong, Jiaxing (Zhong, Jiaxing.) | Li, Yuanli (Li, Yuanli.) | Zhang, Hang (Zhang, Hang.) | Li, Shijie (Li, Shijie.) | Sun, Zaicheng (Sun, Zaicheng.) | Zhuang, Chunqiang (Zhuang, Chunqiang.) (Scholars:庄春强)

Indexed by:

EI Scopus SCIE

Abstract:

To realize the rapid separation of photogenerated carriers in photocatalytic reactions, large-sized porous carbon nanosheets with Pt dots were utilized as cocatalysts and coupled with TiO2 particles to construct photocatalytic systems. The optimized photocatalytic H-2 yield is similar to 108 times higher than that of TiO2, fully demonstrating the important role of large-sized porous carbon nanosheets with Pt dots for fast charge separation. The shift of the main peak in high-resolution X-ray photoelectron spectroscopies (XPS) verifies the electron transfer from TiO2 to porous carbon nanosheets. The dense distribution of photo-induced Pt deposition on porous carbon nanosheets confirms that active centers for H-2 evolution are mainly located on porous carbon nanosheets. Our work here provides the practicability of constructing large-sized conductive materials as cocatalysts for fast charge separation in photocatalytic reactions.

Keyword:

Photocatalytic H-2 Efficient charge separation Porous carbon nanosheet Large-sized cocatalyst

Author Community:

  • [ 1 ] [Zhong, Jiaxing]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yuanli]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Hang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Zhuang, Chunqiang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Shijie]Zhejiang Ocean Univ, Natl Engn Res Ctr Marine Aquaculture, Zhoushan 316022, Zhejiang, Peoples R China
  • [ 6 ] [Sun, Zaicheng]Beijing Univ Technol, Ctr Excellence Environm Safety & Biol Effects, Dept Chem, Beijing Key Lab Green Catalysis & Separat, Beijing, Peoples R China

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2023

Volume: 324

8 . 6 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count: 12

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

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