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Author:

He, Yong (He, Yong.) | Du, Juan (Du, Juan.) | Liu, Shi-ming (Liu, Shi-ming.) | Tian, Chong (Tian, Chong.) | Zhang, Min (Zhang, Min.) | Zhu, Yao-hui (Zhu, Yao-hui.) | Zhong, Hongxia (Zhong, Hongxia.) | Wang, Xinqiang (Wang, Xinqiang.) | Shi, Jun-jie (Shi, Jun-jie.)

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EI Scopus SCIE

Abstract:

The discovery of superconductivity in layered MgB2 has renewed interest in the search for high-temperature conventional superconductors, leading to the synthesis of numerous hydrogen-dominated materials with high critical temperatures (T-c) under high pressures. However, achieving a high-T-c superconductor under ambient pressure remains a challenging goal. In this study, we propose a novel approach to realize a high-temperature superconductor under ambient pressure by introducing a hexagonal H monolayer into the hexagonal close-packed magnesium lattice, resulting in a new and stable few-hydrogen metal-bonded layered magnesium hydride (Mg-4)(2)H-1. This compound exhibits superior ductility compared to multi-hydrogen, cuprate, and iron-based superconductors due to its metallic bonding. Our unconventional strategy diverges from the conventional design principles used in hydrogen-dominated covalent high-temperature superconductors. Using anisotropic Migdal-Eliashberg equations, we demonstrate that the stable (Mg-4)(2)H-1 compound is a typical phonon-mediated superconductor, characterized by strong electron-phonon coupling and an excellent T-c of 37 K under ambient conditions, comparable to that of MgB2. Our findings not only present a new pathway for exploring high-temperature superconductors but also provide valuable insights for future experimental synthesis endeavors.

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Author Community:

  • [ 1 ] [He, Yong]Peking Univ, Yangtze Delta Inst Optoelect, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 2 ] [Liu, Shi-ming]Peking Univ, Yangtze Delta Inst Optoelect, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 3 ] [Tian, Chong]Peking Univ, Yangtze Delta Inst Optoelect, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 4 ] [Wang, Xinqiang]Peking Univ, Yangtze Delta Inst Optoelect, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 5 ] [Shi, Jun-jie]Peking Univ, Yangtze Delta Inst Optoelect, Sch Phys, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 6 ] [Du, Juan]Beijing Univ Technol, Fac Sci, Dept Phys & Optoelect Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, Min]Inner Mongolia Normal Univ, Coll Phys & Elect Informat, Inner Mongolia Key Lab Phys & Chem Funct Mat, Hohhot 010022, Peoples R China
  • [ 8 ] [Zhu, Yao-hui]Beijing Technol & Business Univ, Phys Dept, Beijing 100048, Peoples R China
  • [ 9 ] [Zhong, Hongxia]China Univ Geosci, Sch Math & Phys, Wuhan 430074, Peoples R China

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Source :

PHYSICAL CHEMISTRY CHEMICAL PHYSICS

ISSN: 1463-9076

Year: 2023

Issue: 31

Volume: 25

Page: 21037-21044

3 . 3 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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