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Author:

Zhang, Yuxin (Zhang, Yuxin.) | Jin, Yuhong (Jin, Yuhong.) | Song, Yuanyuan (Song, Yuanyuan.) | Wang, Hao (Wang, Hao.) | Jia, Mengqiu (Jia, Mengqiu.)

Indexed by:

EI Scopus SCIE

Abstract:

Metal sulfide has recently emerged as an attractive anode material for sodium-ion batteries (SIBs) with large layer spacing and desirable electrochemical reversibility, but its low-rate performance and severe volume expansion during cycling immensely hinder further application. In this work, SnS@Co1-xS nanocubes are uniformly anchored in the conductive reduced graphene oxide (rGO) network through a straightforward coprecipitation and vulcanization process. The obtained SnS@Co1-xS-rGO composite with tunable morphologies can achieve the high dispersion of nanoparticles and enhanced charge transfer kinetics simultaneously. Consequently, this SnS@Co1-xS-rGO electrode possesses an impressive cycling performance of 571.23 mAh/g at 0.1 A/ g after 80 cycles and sustains a high-rate capacity of 352.92 mAh/g at a high current density of 10 A/g, which is far outperforming reported tin/cobalt sulfides. It can be demonstrated that rGO plays an important role in the capacity stability of bimetallic sulfides.

Keyword:

SnS@Co 1-x S nanocubes Reduced graphene oxide Sodium-ion batteries Anode materials

Author Community:

  • [ 1 ] [Zhang, Yuxin]Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
  • [ 2 ] [Song, Yuanyuan]Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
  • [ 3 ] [Jia, Mengqiu]Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
  • [ 4 ] [Jin, Yuhong]Beijing Univ Technol, Fac Mat & Mfg, Key Lab New Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Hao]Beijing Univ Technol, Fac Mat & Mfg, Key Lab New Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2023

Volume: 637

6 . 7 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:26

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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