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Abstract:
Metal sulfide has recently emerged as an attractive anode material for sodium-ion batteries (SIBs) with large layer spacing and desirable electrochemical reversibility, but its low-rate performance and severe volume expansion during cycling immensely hinder further application. In this work, SnS@Co1-xS nanocubes are uniformly anchored in the conductive reduced graphene oxide (rGO) network through a straightforward coprecipitation and vulcanization process. The obtained SnS@Co1-xS-rGO composite with tunable morphologies can achieve the high dispersion of nanoparticles and enhanced charge transfer kinetics simultaneously. Consequently, this SnS@Co1-xS-rGO electrode possesses an impressive cycling performance of 571.23 mAh/g at 0.1 A/ g after 80 cycles and sustains a high-rate capacity of 352.92 mAh/g at a high current density of 10 A/g, which is far outperforming reported tin/cobalt sulfides. It can be demonstrated that rGO plays an important role in the capacity stability of bimetallic sulfides.
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APPLIED SURFACE SCIENCE
ISSN: 0169-4332
Year: 2023
Volume: 637
6 . 7 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:26
Cited Count:
WoS CC Cited Count: 8
SCOPUS Cited Count: 9
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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