To　improve　the　air　quality,　volatile　organic　compounds　(VOCs)　elimination　via　a　stable　catalytic　oxidation　is　important.　The　enhancement　in　the　catalytic　stability　of　toluene　and　iso-hexane　removal　is　investigated　by　constructing　the　Pt-Fe　alloy　structure.　The　Pt-Fe　alloy　structure　not　only　weakens　the　toluene　adsorption,　but　also　improves　the　lattice　oxygen　mobility.　The　Mars-van　Krevelen　mechanism　is　presented　over　the　Pt1Fe1.5/M　during　toluene　oxidation,　instead　of　the　initial　Langmuir-Hinshelwood　mechanism.　For　Pt1Fe1.5/M,　the　strong　ability　of　O2　activation　and　the　fast　migration　of　lattice　oxygen　will　provide　sufficient　surface　lattice　oxygen　to　ensure　a　continuous　toluene　oxidation.　An　excellent　catalytic　stability　is　detected　over　the　catalysts　with　the　high　activity　of　lattice　oxygen,　which　are　accelerated　by　the　weaker　adsorption　and　higher　temperature　during　iso-hexane　oxidation.　Generally,　the　crucial　role　of　the　replenishment　speed　of　active　oxygen　species　is　clarified　in　a　stable　process　of　VOCs　oxidation.　It　is　valuable　for　the　up-to-standard　emission　of　VOCs　from　the　furniture　paints　industry.