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Author:

Yu, Rui (Yu, Rui.) | Yang, Yanling (Yang, Yanling.) | Zhou, Zhiwei (Zhou, Zhiwei.) (Scholars:周志伟) | Li, Xing (Li, Xing.) | Liu, Chunjiao (Liu, Chunjiao.) | Sun, Tianjie (Sun, Tianjie.)

Indexed by:

EI Scopus SCIE

Abstract:

In this study, a novel composite based on bismuth oxide, reduced graphene oxide and titanium dioxide (labeled as BRGT) was utilized for visible light photocatalysis to mitigate ultrafiltration membrane fouling caused by natural organic matter (NOM). The results show that the coexistence of NOM and the BRGT composite (without photocatalysis) did not aggravate membrane fouling, and the membrane preferentially retained a high molecular weight, hydrophobic component of NOM that formed a dense cake layer with BRGT composite. As the photo-catalysis time increased, the extent of membrane fouling was alleviated. The maximum specific flux recovered from 0.21 to 0.73 at 60 min, and the hydraulic reversible and irreversible resistances ere 1.15 x 1010 and 4.23 x 1010 m-1, respectively. The reduction of NOM in the feed water, especially the removal of UV254, played a significant role in the alleviation of membrane fouling. Additionally, the changes in the properties of NOM, including the reduction of fluorescent humic and protein/polyphenol components corresponding to reversible and irreversible fouling, respectively, the photo-degradation of high molecular weight NOM into low molecular weight NOM (such as low molecular weight-acids), and the conversion of hydrophobic fractions into hydrophilic fractions, contributed to the mitigation of membrane fouling. We also found a strong negative correlation be-tween the roughness of the cake layer and irreversible fouling. Overall, the changes in the properties of NOM in feed water can hinder or even inhibit the formation of the cake layer, and the use of visible light photocatalysis of the BRGT composite has great potential to alleviate ultrafiltration membrane fouling caused by natural organic matter.

Keyword:

Mechanism of fouling development Fouling mitigation Ultrafiltration Natural organic matter Visible light photocatalysis

Author Community:

  • [ 1 ] [Yu, Rui]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construct, Beijing 100124, Peoples R China
  • [ 2 ] [Yang, Yanling]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construct, Beijing 100124, Peoples R China
  • [ 3 ] [Zhou, Zhiwei]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construct, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Xing]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construct, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Chunjiao]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construct, Beijing 100124, Peoples R China
  • [ 6 ] [Sun, Tianjie]Beijing Univ Technol, Coll Architecture & Civil Engn, Fac Urban Construct, Beijing 100124, Peoples R China
  • [ 7 ] [Yang, Yanling]Beijing Univ Technol, 100 Xi Da Wang Rd, Beijing 100124, Peoples R China

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2023

Volume: 324

8 . 6 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:20

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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