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Author:

Huilin LUN (Huilin LUN.) | Yi ZENG (Yi ZENG.) | Xiang XIONG (Xiang XIONG.) | Ziming YE (Ziming YE.) | Zhongwei ZHANG (Zhongwei ZHANG.) | Xingchao LI (Xingchao LI.) | Haikun CHEN (Haikun CHEN.) | Yufeng LIU (Yufeng LIU.)

Abstract:

Multi-component solid solutions with non-stoichiometric compositions are characteristics of ultra-high temperature carbides as promising materials for hypersonic vehicles.However,for groupⅣ transition-metal carbides,the oxidation behavior of multi-component non-stoichiometric(Zr,Hf,Ti)Cx carbide solid solution has not been clarified yet.The present work fabricated four kinds of (Zr,Hf,Ti)Cx carbide solid solution powders by free-pressureless spark plasma sintering to investigate the oxidation behavior of (Zr,Hf,Ti)Cx in air.The effects of metallic atom composition on oxidation resistance were examined.The results indicate that the oxidation kinetics of (Zr,Hf,Ti)Cx are composition dependent.A high Hf content in (Zr,Hf,Ti)Cx was beneficial to form an amorphous Zr-Hf-Ti-C-O oxycarbide layer as an oxygen barrier to enhance the initial oxidation resistance.Meanwhile,an equiatomic ratio of metallic atoms reduced the growth rate of (Zr,Hf,Ti)O2 oxide,increasing its phase stability at high temperatures,which improved the oxidation activation energy of(Zr,Hf,Ti)Cx.

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Author Community:

  • [ 1 ] [Xingchao LI]Science and Technology of Advanced Functional Composites Laboratory,Aerospace Research Institute of Materials & Processing Technology,Beijing 100076,China
  • [ 2 ] [Zhongwei ZHANG]北京工业大学
  • [ 3 ] [Huilin LUN]中南大学
  • [ 4 ] [Ziming YE]中南大学
  • [ 5 ] [Xiang XIONG]中南大学
  • [ 6 ] [Haikun CHEN]Science and Technology of Advanced Functional Composites Laboratory,Aerospace Research Institute of Materials & Processing Technology,Beijing 100076,China
  • [ 7 ] [Yi ZENG]中南大学
  • [ 8 ] [Yufeng LIU]State Key Laboratory of Powder Metallurgy,Central South University,Changsha 410083,China;Science and Technology of Advanced Functional Composites Laboratory,Aerospace Research Institute of Materials & Processing Technology,Beijing 100076,China

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Source :

先进陶瓷(英文版)

ISSN: 2226-4108

Year: 2021

Issue: 4

Volume: 10

Page: 741-757

1 6 . 9 0 0

JCR@2022

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count: -1

Chinese Cited Count:

30 Days PV: 11

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