Radical-polar　crossover　(RPC)　reaction　bridges　the　gap　between　one-　and　two-electron　reactivities,　thus　providing　an　ideal　solution　to　overcome　the　limitations　of　both　radical　and　polar　chemistry.　In　this　manifold,　organic　electrochemistry　provides　a　uniquely　facile　strategy　to　access　a　diverse　array　of　radical　intermediates,　thus　broadening　the　chemical　space　of　the　RPC　concept.　This　review　highlights　the　synthetic　advances　in　the　field　of　electrochemical　RPC　reactions　since　2020,　with　an　emphasis　on　the　substrate　scope,　reaction　limitation　and　mechanistic　aspect.　The　related　RPC　reactions　are　categorized　as　net-oxidative,　net-reductive,　or　redox　neutral　transformations.