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Author:

Li, Jingjie (Li, Jingjie.) | Kang, Qian (Kang, Qian.) | Wang, Yanhao (Wang, Yanhao.) | Zhou, Zixiao (Zhou, Zixiao.) | Sun, Zhaoqing (Sun, Zhaoqing.) | Zhang, Hai (Zhang, Hai.) | Lu, Wanyu (Lu, Wanyu.) | Tao, Xianglin (Tao, Xianglin.) | Zhang, Shan-Ting (Zhang, Shan-Ting.) | Chen, Xiaoqing (Chen, Xiaoqing.) | Zheng, Zilong (Zheng, Zilong.) | Yan, Hui (Yan, Hui.) | Li, Dongdong (Li, Dongdong.) | Zhang, Yongzhe (Zhang, Yongzhe.)

Indexed by:

EI Scopus SCIE

Abstract:

In crystalline silicon (c-Si) solar cells, the hole transport layer (HTL) made of high oxygen content MoOx (x > 2.85, H-MoOx) evaporating from molybdenum trioxide is not ideal due to low optical bandgap and interface reaction effects. This limits the power conversion efficiency (PCE) and stability of c-Si solar cells. To improve this, low oxygen content MoOx (x < 2.85, L-MoOx) with a wide bandgap of 3.87 eV, deposited using molybdenum dioxide (MoO2), is explored and implemented. The c-Si/SiOx (FGA, forming gas annealing)/L-MoOx heterojunction has a low contact resistivity of approximate to 15.06 m Omega cm(2), which is almost one order of magnitude lower than that of c-Si/SiOx(FGA)/H-MoOx heterojunction. Using L-MoOx as the HTL, a c-Si solar cell based on the SiOx passivation layer shows a fill factor of 84.38% and PCE of 21.75%, representing the highest efficiency for MoOx-based p-type c-Si solar cells. Scanning transmission electron microscopy results show that the L-MoOx HTL effectively enhances the stability of c-Si solar cells when exposed to air by reducing Ag and Si element diffusion into MoOx. This successful preparation of efficient and stable MoOx HTL films, while preserving their field-effect passivation ability, provides valuable insights into the development of high-performance HTL.

Keyword:

crystalline silicon solar cell performance stability MoOx hole transport layer power conversion efficiency

Author Community:

  • [ 1 ] [Li, Jingjie]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Zhou, Zixiao]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Sun, Zhaoqing]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Lu, Wanyu]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Tao, Xianglin]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Zheng, Zilong]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 7 ] [Yan, Hui]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 8 ] [Kang, Qian]Beijing Univ Technol, Fac Informat Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China
  • [ 9 ] [Zhang, Hai]Beijing Univ Technol, Fac Informat Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China
  • [ 10 ] [Chen, Xiaoqing]Beijing Univ Technol, Fac Informat Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China
  • [ 11 ] [Zhang, Yongzhe]Beijing Univ Technol, Fac Informat Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China
  • [ 12 ] [Wang, Yanhao]Chinese Acad Sci, Shanghai Adv Res Inst, Interdisciplinary Res Ctr, 99 Haike Rd,Zhangjiang Hitech Pk, Shanghai 201210, Peoples R China
  • [ 13 ] [Wang, Yanhao]Univ Chinese Acad Sci, Sch Integrated Circuits, Beijing 100000, Peoples R China
  • [ 14 ] [Zhang, Shan-Ting]Zhangjiang Lab, 100 Haike Rd,Zhangjiang Hitech Pk, Shanghai 201210, Peoples R China
  • [ 15 ] [Li, Dongdong]Zhangjiang Lab, 100 Haike Rd,Zhangjiang Hitech Pk, Shanghai 201210, Peoples R China

Reprint Author's Address:

  • [Kang, Qian]Beijing Univ Technol, Fac Informat Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China;;[Zhang, Yongzhe]Beijing Univ Technol, Fac Informat Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China;;[Li, Dongdong]Zhangjiang Lab, 100 Haike Rd,Zhangjiang Hitech Pk, Shanghai 201210, Peoples R China;;

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2023

Issue: 6

Volume: 34

1 9 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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