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Author:

Haseeb, M. (Haseeb, M..) | Li, Y.Q. (Li, Y.Q..) | Zhang, H.G. (Zhang, H.G..) | Liu, W.Q. (Liu, W.Q..) | Zhang, P.J. (Zhang, P.J..) | Yue, M. (Yue, M..)

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Scopus SCIE

Abstract:

M-type ferrite exhibits good magnetic characteristics and resistance to oxidation, enabling the production of stable nanoparticles for applications such as medical delivery, hyperthermia therapy, and magnetic recording. Additionally, it serves as a valuable tool for studying the theory of coercivity. Here, the impact of surface and size on coercivity and associated mechanisms in M-type hexagonal ferrites has been thoroughly analyzed by a combination of micromagnetic models and experimental investigations. Based on a cubic model and without considering surface defects, the coercivity still cannot reach the theoretical value. It decreases with an increase in particle size, and the quasi-coherent and quasi-flower reversal modes appear continuously. Besides, surface defects do not affect the reversal mode, but they do decrease the coercivity and magnetic hardening effect, hence further amplifying the difference between coercivity and its theoretical value. The simulation results are strongly supported by experimental data. This study extensively examines the coercivity of M-type ferrite particles produced by various preparation methods, taking into account experimental observations and simulation results. Our findings can serve as guidance for the development of preparation technology for permanent magnet nanoparticles and contribute to a deeper understanding of the contradictions in coercivity and the mechanisms of magnetization reversal. © 2024

Keyword:

Hexagonal ferrites Magnetization reversal mechanism Surface defects Coercivity Micromagnetic simulations

Author Community:

  • [ 1 ] [Haseeb M.]College of Materials Science & Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Li Y.Q.]College of Materials Science & Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Zhang H.G.]College of Materials Science & Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Liu W.Q.]College of Materials Science & Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Zhang P.J.]BGRIMM Magnetic Materials and Technology Co., Ltd., Beijing, 102600, China
  • [ 6 ] [Yue M.]College of Materials Science & Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing, 100124, China

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Source :

Surfaces and Interfaces

ISSN: 2468-0230

Year: 2024

Volume: 46

6 . 2 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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