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Author:

Yu-Long Liao (Yu-Long Liao.) | Jiang-Kui Hu (Jiang-Kui Hu.) | Zhong-Heng Fu (Zhong-Heng Fu.) | Chen-Zi Zhao (Chen-Zi Zhao.) | Yang Lu (Yang Lu.) | Shuai Li (Shuai Li.) | Shi-Jie Yang (Shi-Jie Yang.) | Shuo Sun (Shuo Sun.) | Xi-Long Wang (Xi-Long Wang.) | Jia Liu (Jia Liu.) | Jia-Qi Huang (Jia-Qi Huang.) | Hong Yuan (Hong Yuan.)

Abstract:

All-solid-state lithium metal batteries(ASSLMBs)are considered as one of the ultimate goals for the development of energy storage systems due to their high energy density and high safety.However,the mismatching of interface transport kinetics as well as interfacial instability induces the growth of lithium dendrite and thus,leads to severe degradation of battery electrochemical performances.Herein,an inte-grated interface configuration(IIC)consisting of in-situ generated Lil interphase and Li-Ag alloy anode is proposed through in-situ interface chemistry.The IIC is capable of not only regulating charge transport kinetics but also synchronously stabilizing the lithium/electrolyte interface,thereby achieving uniform lithium platting.Therefore,Li||Li symmetric cells with IIC achieve a critical current density of up to 1.6 mA cm-2 and achieve stable cycling over 1600 hours at a high current density of 0.5 mA cm-2.Moreover,a high discharge capacity of 140.1 mA h g-1 at 0.1 C is also obtained for the Li(Ni0.6Co0.2Mno.2)O2(NCM622)full battery with a capacity retention of 65.6%after 300 cycles.This work provides an effective method to synergistically regulate the interface transport kinetics and inhibit lithium dendrite growth for high-performance ASSLMBs.

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Author Community:

  • [ 1 ] [Yang Lu]清华大学
  • [ 2 ] [Hong Yuan]School of Materials Science & Engineering,Beijing Institute of Technology,Beijing 100081,China;Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing 100081,China
  • [ 3 ] [Shi-Jie Yang]School of Materials Science & Engineering,Beijing Institute of Technology,Beijing 100081,China;Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing 100081,China
  • [ 4 ] [Jia Liu]北京林业大学
  • [ 5 ] [Shuai Li]School of Materials Science & Engineering,Beijing Institute of Technology,Beijing 100081,China;Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing 100081,China
  • [ 6 ] [Zhong-Heng Fu]清华大学
  • [ 7 ] [Yu-Long Liao]School of Materials Science & Engineering,Beijing Institute of Technology,Beijing 100081,China;Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing 100081,China
  • [ 8 ] [Jiang-Kui Hu]School of Materials Science & Engineering,Beijing Institute of Technology,Beijing 100081,China;Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing 100081,China
  • [ 9 ] [Xi-Long Wang]School of Materials Science & Engineering,Beijing Institute of Technology,Beijing 100081,China;Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing 100081,China
  • [ 10 ] [Chen-Zi Zhao]北京工业大学
  • [ 11 ] [Jia-Qi Huang]School of Materials Science & Engineering,Beijing Institute of Technology,Beijing 100081,China;Advanced Research Institute of Multidisciplinary Science,Beijing Institute of Technology,Beijing 100081,China
  • [ 12 ] [Shuo Sun]清华大学

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Source :

能源化学

ISSN: 2095-4956

Year: 2023

Issue: 5

Volume: 80

Page: 458-465

1 3 . 1 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count: -1

Chinese Cited Count:

30 Days PV: 6

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