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Author:

Zhu, Liangliang (Zhu, Liangliang.) | Huang, Shuai (Huang, Shuai.) | Liu, Yue (Liu, Yue.) | Li, Ruixuan (Li, Ruixuan.) | Zhang, Guangyin (Zhang, Guangyin.) | Chen, Yanzhong (Chen, Yanzhong.) | Dong, Guifang (Dong, Guifang.) | Zhang, Xinping (Zhang, Xinping.) | Guan, Baolu (Guan, Baolu.) (Scholars:关宝璐)

Indexed by:

EI Scopus SCIE

Abstract:

Halide perovskite materials are considered a promising optical gain medium for stimulated emission and have aroused tremendous interest in the field of laser research. The development of low-threshold optically pumped amplified spontaneous emission (ASE) is critical for the advancement of continuous wave (CW) and electrically pumped micro-nano lasers. In this work, an efficient ZnS additive is incorporated into the FA0.85MA0.15PbI2.55Br0.45 perovskite films to diminish the ASE threshold and extend the photostability by the dual-site synergistic passivation. The experimental measurements and first-principles calculations based on the density functional theory (DFT) are employed to elucidate the doping mechanism. The designed ZnS-based perovskite films yield a mitigated ASE threshold of 8.5 mu J cm-2 with an elevated optical gain coefficient of 109.06 cm-1, which outperform those of the control films (12.7 mu J cm-2 and 74.10 cm-1). The in-depth experimental characterizations and theoretical calculations have corroborated that the improvement of ASE performance can be ascribed to the dual-site synergistic passivation effects of Zn2+ and S2-, which reduces the surface defects of perovskite films, suppresses the nonradiative charge recombination and improves the optical stability. This work provides a resultful strategy to construct the solution-processed perovskite lasers with low thresholds and superior stability. Through dual-site synergistic passivation effects, Zn2+ enters the lattice as interstitials, and S2- fills the I/Br vacancies, which synergistically improves the perovskite ASE properties. The doped films show a longer fluorescence lifetime and better stability than the pristine perovskite films. image

Keyword:

reduced threshold optical gain ZnS perovskites amplified spontaneous emission

Author Community:

  • [ 1 ] [Zhu, Liangliang]Beijing Univ Technol, Coll Elect Sci & Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Huang, Shuai]Beijing Univ Technol, Coll Elect Sci & Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Guan, Baolu]Beijing Univ Technol, Coll Elect Sci & Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Liu, Yue]Beijing Univ Technol, Inst Informat Photon Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Xinping]Beijing Univ Technol, Inst Informat Photon Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Li, Ruixuan]Chinese Acad Sci, Aerosp Informat Res Inst, Beijing 10094, Peoples R China
  • [ 7 ] [Zhang, Guangyin]Chinese Acad Sci, Aerosp Informat Res Inst, Beijing 10094, Peoples R China
  • [ 8 ] [Chen, Yanzhong]Chinese Acad Sci, Aerosp Informat Res Inst, Beijing 10094, Peoples R China
  • [ 9 ] [Dong, Guifang]Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China

Reprint Author's Address:

  • 关宝璐

    [Huang, Shuai]Beijing Univ Technol, Coll Elect Sci & Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China;;[Guan, Baolu]Beijing Univ Technol, Coll Elect Sci & Technol, Key Lab Optoelect Technol, Minist Educ, Beijing 100124, Peoples R China

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Source :

LASER & PHOTONICS REVIEWS

ISSN: 1863-8880

Year: 2024

Issue: 8

Volume: 18

1 1 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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