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Halide perovskite materials are considered a promising optical gain medium for stimulated emission and have aroused tremendous interest in the field of laser research. The development of low-threshold optically pumped amplified spontaneous emission (ASE) is critical for the advancement of continuous wave (CW) and electrically pumped micro-nano lasers. In this work, an efficient ZnS additive is incorporated into the FA0.85MA0.15PbI2.55Br0.45 perovskite films to diminish the ASE threshold and extend the photostability by the dual-site synergistic passivation. The experimental measurements and first-principles calculations based on the density functional theory (DFT) are employed to elucidate the doping mechanism. The designed ZnS-based perovskite films yield a mitigated ASE threshold of 8.5 mu J cm-2 with an elevated optical gain coefficient of 109.06 cm-1, which outperform those of the control films (12.7 mu J cm-2 and 74.10 cm-1). The in-depth experimental characterizations and theoretical calculations have corroborated that the improvement of ASE performance can be ascribed to the dual-site synergistic passivation effects of Zn2+ and S2-, which reduces the surface defects of perovskite films, suppresses the nonradiative charge recombination and improves the optical stability. This work provides a resultful strategy to construct the solution-processed perovskite lasers with low thresholds and superior stability. Through dual-site synergistic passivation effects, Zn2+ enters the lattice as interstitials, and S2- fills the I/Br vacancies, which synergistically improves the perovskite ASE properties. The doped films show a longer fluorescence lifetime and better stability than the pristine perovskite films. image
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LASER & PHOTONICS REVIEWS
ISSN: 1863-8880
Year: 2024
Issue: 8
Volume: 18
1 1 . 0 0 0
JCR@2022
Cited Count:
WoS CC Cited Count: 0
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 7
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