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Author:

Song, X. (Song, X..) | Yang, Z. (Yang, Z..) | Wu, Y. (Wu, Y..) | Chang, Y. (Chang, Y..) | Song, H. (Song, H..) | Zhou, W. (Zhou, W..) | Wang, J. (Wang, J..) | Li, H. (Li, H..)

Indexed by:

EI Scopus SCIE

Abstract:

Designing low-cost catalysts that offer both high mass activity and high cycling stability is crucial. Herein, a binder-free 3D self-supporting electrode composed of carbo-nitride tungsten supporting Pt nanoparticles (Pt@3DP-WNxC1-x/W) has been successfully synthesized for hydrogen evolution reaction in acid electrolyte. The tungsten carbo-nitride synthesized via a one-step heat treatment exhibits enhanced conductivity as a result of the carbonization process and optimizes the adsorption and desorption properties of WC towards H atoms through the incorporation of N atoms, thereby achieving an effective balance. Simultaneously, the N–Pt bond enhances electron transfer efficiency. This electrode exhibits outstanding electrochemical performance with a 219 mV overpotential at a current density of −300 mA cm−2. Its current density and mass activity is up to 75 mA cm−2 and 7.5 A·mgPt−1 at an overpotential of 100 mV, respectively, which are both 2.6 times higher than those of the 40% Pt/C electrode. In addition, it reveals a low Tafel slope of 38.3 mV dec−1 indicating rapid kinetics. Furthermore, the electrocatalyst shows only 3 mV day at −100 mA cm−2 after 10,000 cycles. Both theoretical calculation and experimental results show the promotion of catalytic efficiency of Pt@3DP-WNxC1-x/W brought by carbo-nitrition. This study offers a novel, efficient, and stable electrode design strategy. © 2024 Elsevier B.V.

Keyword:

Electrodeposition Self-supporting Tungsten Carbonitriding Hydrogen evolution reaction

Author Community:

  • [ 1 ] [Song X.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Yang Z.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Wu Y.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Chang Y.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Song H.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Zhou W.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 7 ] [Wang J.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 8 ] [Li H.]Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing, 100124, China
  • [ 9 ] [Li H.]College of Carbon Neutrality Future Technology, Beijing University of Technology, Beijing, 100124, China

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2024

Volume: 604

9 . 2 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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