Please Login >
English| 简体中文

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Advanced Search

Author：

Lin, H. (Lin, H..) | Liu, Y. (Liu, Y..) | Deng, J. (Deng, J..) | Jing, L. (Jing, L..) | Wang, Z. (Wang, Z..) | Wei, L. (Wei, L..) | Hou, Z. (Hou, Z..) | Tao, J. (Tao, J..) | Dai, H. (Dai, H..)

Indexed by：

EI Scopus SCIE

Abstract：

Three-dimensionally　ordered　macroporous　(3DOM)　Ce0.7Zr0.3O2-supported　Pd　(xPd/3DOM　Ce0.7Zr0.3O2,　x　=　0.97,　1.49,　and　2.10　wt%)　catalysts　were　fabricated　using　the　polymethyl　methacrylate　(PMMA)　microsphere-templating　and　polyvinyl　alcohol　(PVA)-protected　reduction　methods.　It　was　found　that　the　xPd/3DOM　Ce0.7Zr0.3O2　samples　with　surface　areas　of　31.9−38.2　m2/g　possessed　a　high-quality　3DOM　architecture,　with　the　Pd　nanoparticles　(NPs)　being　uniformly　dispersed　on　the　3DOM　Ce0.7Zr0.3O2　surface.　Among　all　of　the　samples,　1.49　Pd/3DOM　Ce0.7Zr0.3O2　showed　the　best　CH4　combustion　activity:　The　T10%,　T50%,　and　T90%　(the　temperatures　at　CH4　conversions　=　10,　50,　and　90%)　were　269,　330,　and　380　°C,　respectively;　specific　reaction　rate　at　260　°C　was　115.0　×　10−6　mol/(gPd　s),　and　turnover　frequency　at　260　°C　(TOFPd)　was　28.8　×　10−3　s−1.　The　good　catalytic　performance　of　1.49　Pd/3DOM　Ce0.7Zr0.3O2　was　associated　with　the　well-defined　3DOM　structure,　high　Pd　NP　dispersion,　rich　adsorbed　oxygen　species,　and　strong　interaction　between　Pd　NPs　and　3DOM　Ce0.7Zr0.3O2.　Interestingly,　the　1.49　Pd/3DOM　Ce0.7Zr0.3O2　sample　also　exhibited　superior　water-tolerant　performance.　The　product　analysis　results　after　the　in　situ　introduction　of　isotopic　water　demonstrated　that　the　excellent　water　resistance　of　1.49　Pd/3DOM　Ce0.7Zr0.3O2　was　due　to　the　interaction　of　oxygen　and　water　to　form　the　peroxy　hydroxyl　species　on　the　sample　surface　after　the　water　pretreatment,　which　was　beneficial　for　the　combustion　of　methane.　©　2024　Elsevier　B.V.

Keyword：

Supported palladium catalyst Ceria−zirconia solid solution Three-dimensionally ordered macropore Methane combustion Water resistance

Author Community：

  • [ 1 ] [Lin H.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Lin H.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Liu Y.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Liu Y.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Deng J.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Deng J.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 7 ] [Jing L.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 8 ] [Jing L.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 9 ] [Wang Z.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 10 ] [Wang Z.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 11 ] [Wei L.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 12 ] [Wei L.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 13 ] [Hou Z.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 14 ] [Hou Z.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 15 ] [Tao J.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 16 ] [Tao J.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 17 ] [Dai H.]Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemical Engineering and Technology, College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 18 ] [Dai H.]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental Science and Engineering, Beijing University of Technology, Beijing, 100124, China

Reprint Author's Address：

Email：

Show more details

Related Keywords：

Related Article：

Source ：

Catalysis Today

ISSN： 0920-5861

Year： 2024

Volume： 434

5 . 3 0 0

JCR@2022

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 2

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS
Online/Total：881/10581532
Address：BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code：100124) Contact Us：010-67392185
Copyright：BJUT Library Technical Support：Beijing Aegean Software Co., Ltd.