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Author:

Pang, Wenlong (Pang, Wenlong.) | Li, Bin (Li, Bin.) | Wu, Yufeng (Wu, Yufeng.) | Zeng, Qing (Zeng, Qing.) | Yang, Jun (Yang, Jun.) | Zhang, Yu (Zhang, Yu.) | Tian, Shaonan (Tian, Shaonan.)

Indexed by:

EI Scopus SCIE

Abstract:

Biodegradable plastics such as Poly (butylene adipate-co-terephthalate) (PBAT) have been extensively utilized in numerous fields. However, post-consumption, PBAT tends to pollute the environment and waste resources. Herein, a novel approach employing a 1,4-butanediol-alkali combined method for the hydrolysis of PBAT is introduced. At 130 degrees C, with a reaction time of 60 min, the hydrolysis rate of PBAT exceeds 99 %. Subsequently, a two-step synthesis rapidly produces a foam nickel-supported NiOOH catalyst for the electrocatalytic reformation of the PBAT hydrolysate into higher-value chemicals (succinate salts) at an impressive current density of 100 mA cm(-2) at 1.43 V (vs. RHE) and a Faradaic efficiency of 97.6 %. Experimental results and density functional theory calculations have elucidated the active state changes of the foam nickel-supported NiOOH catalyst and the intermediates in the oxidation of 1,4-butanediol to succinate, alongside the reaction mechanism. This study offers a viable approach for the degradation of PBAT plastic through a 1,4-butanediol-alkali method and the rapid preparation of a foam nickel-supported NiOOH electrocatalyst, achieving the upgraded recycling of post-consumer biodegradable PBAT plastic.

Keyword:

1,4-Butanediol-alkali combined method Upgraded recycling PBAT Density Functional Theory NiOOH

Author Community:

  • [ 1 ] [Pang, Wenlong]Beijing Univ Technol, Inst Circular Econ, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Bin]Beijing Univ Technol, Inst Circular Econ, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wu, Yufeng]Beijing Univ Technol, Inst Circular Econ, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Pang, Wenlong]Chinese Acad Sci, Inst Proc Engn, State Key Lab Mesosci & Engn, Beijing 100190, Peoples R China
  • [ 5 ] [Zeng, Qing]Chinese Acad Sci, Inst Proc Engn, State Key Lab Mesosci & Engn, Beijing 100190, Peoples R China
  • [ 6 ] [Yang, Jun]Chinese Acad Sci, Inst Proc Engn, State Key Lab Mesosci & Engn, Beijing 100190, Peoples R China
  • [ 7 ] [Zhang, Yu]Chinese Acad Sci, Inst Proc Engn, State Key Lab Mesosci & Engn, Beijing 100190, Peoples R China
  • [ 8 ] [Tian, Shaonan]Chinese Acad Sci, Inst Proc Engn, State Key Lab Mesosci & Engn, Beijing 100190, Peoples R China

Reprint Author's Address:

  • [Wu, Yufeng]Beijing Univ Technol, Inst Circular Econ, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Tian, Shaonan]Chinese Acad Sci, Inst Proc Engn, State Key Lab Mesosci & Engn, Beijing 100190, Peoples R China;;

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2024

Volume: 486

1 5 . 1 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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