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Author:

Wang, Yuanpeng (Wang, Yuanpeng.) | Liu, Quanyi (Liu, Quanyi.) | Tian, Lu (Tian, Lu.) | Hao, Zhihong (Hao, Zhihong.) | Zhang, Lei (Zhang, Lei.) | Fu, Qi (Fu, Qi.) | Zhao, Jinliang (Zhao, Jinliang.) | Mo, Zhaojun (Mo, Zhaojun.)

Indexed by:

EI Scopus SCIE

Abstract:

Adiabatic demagnetization refrigeration (ADR) technology has the advantage of not relying on helium-3 resources and gravity compared to traditional ultra-low temperature refrigeration technology. The key to the development of ADR technology is finding magnetic refrigeration materials with brilliant magnetocaloric properties. In this study, polycrystalline EuB 2 O 4 was successfully prepared by solid-phase reaction method. The analysis of magnetic susceptibility curves and first-principles calculations reveals a magnetic phase transition from antiferromagnetic (AFM) to paramagnetic (PM) of EuB 2 O 4 , with T N = 0.72 K. The magnetic entropy change (- Delta S M ) is evaluated up to 5 T, with the maximum value of 19.4 J & sdot; kg - 1 K -1 (88.7 mJ & sdot; cm - 3 K -1 ), 35.0 J & sdot; kg - 1 K -1 (160.0 mJ & sdot; cm - 3 K -1 ) and 50.8 J & sdot; kg - 1 K - 1 (232.2 mJ & sdot; cm - 3 K -1 ) at around T = 1.3 K and under mu 0 Delta H = 1 T, 2 T and 5 T, respectively, which were significantly higher than those of the commercial magnetic refrigerant Gd 3 Ga 5 O 12 . The large - Delta S M suggest that EuB 2 O 4 is a potentially great magnetic refrigerant for obtaining ultralow temperature.

Keyword:

Ultra-low temperature Magnetocaloric effect

Author Community:

  • [ 1 ] [Wang, Yuanpeng]Univ Sci & Technol China, Sch Rare Earths, Hefei 230026, Peoples R China
  • [ 2 ] [Mo, Zhaojun]Univ Sci & Technol China, Sch Rare Earths, Hefei 230026, Peoples R China
  • [ 3 ] [Wang, Yuanpeng]Chinese Acad Sci, Ganjiang Innovat Acad, Key Lab Rare Earths, Ganzhou 341000, Peoples R China
  • [ 4 ] [Liu, Quanyi]Chinese Acad Sci, Ganjiang Innovat Acad, Key Lab Rare Earths, Ganzhou 341000, Peoples R China
  • [ 5 ] [Tian, Lu]Chinese Acad Sci, Ganjiang Innovat Acad, Key Lab Rare Earths, Ganzhou 341000, Peoples R China
  • [ 6 ] [Zhang, Lei]Chinese Acad Sci, Ganjiang Innovat Acad, Key Lab Rare Earths, Ganzhou 341000, Peoples R China
  • [ 7 ] [Fu, Qi]Chinese Acad Sci, Ganjiang Innovat Acad, Key Lab Rare Earths, Ganzhou 341000, Peoples R China
  • [ 8 ] [Mo, Zhaojun]Chinese Acad Sci, Ganjiang Innovat Acad, Key Lab Rare Earths, Ganzhou 341000, Peoples R China
  • [ 9 ] [Hao, Zhihong]Gannan Univ Sci & Technol, Sch Rare Earth & New Mat Engn, Ganzhou 341000, Peoples R China
  • [ 10 ] [Liu, Quanyi]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China
  • [ 11 ] [Zhao, Jinliang]Beijing Univ Technol, Fac Sci, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Mo, Zhaojun]Univ Sci & Technol China, Sch Rare Earths, Hefei 230026, Peoples R China;;

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2024

Volume: 995

6 . 2 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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