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Author:

Yang, Dahai (Yang, Dahai.) | Huang, Rui (Huang, Rui.) | Zou, Bolin (Zou, Bolin.) | Zhang, Xingyu (Zhang, Xingyu.) | Ang, Edison Huixiang (Ang, Edison Huixiang.) | Wang, Yong (Wang, Yong.) | Sun, Yi (Sun, Yi.) | Xiang, Hongfa (Xiang, Hongfa.) | Song, Xiaohui (Song, Xiaohui.)

Indexed by:

EI Scopus SCIE

Abstract:

Understanding the volume expansion behavior of Si anodes and their interaction with electrolyte environments is crucial for developing high-performance lithium-ion batteries (LIBs). This study utilizes a graphene liquid cell for in situ imaging to systematically investigate the volume expansion and etching behavior of Si anode nanoparticles in different electrolyte environments. Comparative experiments on Si@C core-shell nanoparticles assess their volume expansion dynamics. The findings reveal significant variation in the expansion rate of nano Si depending on the electrolyte environment, with chemical etching observed under specific conditions. Conversely, Si@C core-shell structures show mitigated expansion due to the confinement effect of the carbon matrix. Battery performance experiments validate these results, demonstrating the excellent cycling stability of Si@C anodes. Various coating agents are explored to optimize Si@C structures, with dopamine thin layer coating exhibiting the best cycling stability. This study offers fundamental insights into Si anode expansion, electrolyte effects, and carbon coating impacts, advancing LIB technology.

Keyword:

Volume expansion Lithium battery In situ liquid phase TEM Core-shell nanoparticles Si anode

Author Community:

  • [ 1 ] [Yang, Dahai]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 2 ] [Huang, Rui]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 3 ] [Zou, Bolin]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 4 ] [Sun, Yi]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 5 ] [Xiang, Hongfa]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 6 ] [Song, Xiaohui]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 7 ] [Zhang, Xingyu]Beijing Univ Technol, Sch Math Stat & Mech, Beijing 100124, Peoples R China
  • [ 8 ] [Ang, Edison Huixiang]Nanyang Technol Univ, Natl Inst Educ, Nat Sci & Sci Educ, Singapore 637616, Singapore
  • [ 9 ] [Wang, Yong]Jiangsu Univ, Inst Energy Res, Zhenjiang 212013, Jiangsu, Peoples R China

Reprint Author's Address:

  • [Song, Xiaohui]Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China;;

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Source :

NANO TODAY

ISSN: 1748-0132

Year: 2024

Volume: 57

1 7 . 4 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Affiliated Colleges:

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