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Local symmetry of crystal field is crucial for optical temperature sensitivity that based on the thermal couple levels of rare earth ions. In this work, Lu3+ ions were introduced to alter the local environment of Er3+ ions in oxyfluoride glass-ceramics. X-ray diffraction patterns and transmission electron microscope images show that Y5O4F7 nanocrystals are precipitated in glass-ceramics. Incorporation of rare-earth ions into the Y5O4F7 nanocrystals is confirmed by absorption and electron energy loss spectra. The Judd-Ofelt (J-O) theory analysis reveals that local symmetry of the crystal field around Er3+ decreasing due to Lu3+ co-doping. Temperature sensing property of the Y5O4F7: Er3+/Yb3+/Lu3+ nanocrystal incorporated glass-ceramic was investigated, and the optimal relative temperature sensitivity SR reaches 1.50 % K−1 in 0.25 mol.% Lu3+ doped specimen. Results show that the moderate addition of Lu3+ can improve the temperature sensitivity of glass-ceramic containing Y5O4F7:Er3+/Yb3+ nanocrystals, which provide a promising avenue for optical temperature sensing. © 2024 Elsevier Ltd and Techna Group S.r.l.
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Ceramics International
ISSN: 0272-8842
Year: 2024
Issue: 18
Volume: 50
Page: 33472-33479
5 . 2 0 0
JCR@2022
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30 Days PV: 4
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