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Author:

Li, Xiyang (Li, Xiyang.) | Wang, Ziyuan (Wang, Ziyuan.) | Qin, Xia (Qin, Xia.) | Zhang, Fanbin (Zhang, Fanbin.) | Xu, Cuicui (Xu, Cuicui.) | Tao, Xingwei (Tao, Xingwei.) | Ren, Hongyun (Ren, Hongyun.) | Lan, Xujie (Lan, Xujie.)

Indexed by:

EI Scopus SCIE

Abstract:

This study introduced a novel catalyst, Cu-Fe@CTS (Chitosan)-ATP (attapulgite), which distinguished itself from traditional Fenton-like catalysts by effectively degrading pollutants across a broad pH range. This catalyst achieved impressive degradation rates of 200 mg L -1 of FA (Fulvic acid), reaching 97 % at pH = 3, 96 % at pH = 7, and 95 % at pH = 10. The catalyst 's enduring effectiveness, with FA removal rates marginal decrease to 94 % at pH = 3 after ten cycles, showcased its sustained catalytic activity. The underlying mechanism was attributed to a synergistic interaction facilitated by the addition of Cu 2+ and Fe 3+ into ATP 's framework, which generated a M 1 -O -M 2 structure. Experimentation and analysis revealed a dynamic electron transfer mechanism within the M 1 -O -M 2 structure. Moreover, the catalyst proved to be highly effective in treating real wastewater-leachate concentrate, underscoring its potential for environmental remediation across diverse pH conditions. This research laid the groundwork for expanding the pH applicability of catalysts, opening new pathways for advanced environmental clean-up strategies.

Keyword:

Wide pH range Heterogeneous Fenton-like reaction Lewis acids Electron transport Bimetallic

Author Community:

  • [ 1 ] [Li, Xiyang]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Ziyuan]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 3 ] [Qin, Xia]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Fanbin]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 5 ] [Xu, Cuicui]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 6 ] [Tao, Xingwei]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 7 ] [Ren, Hongyun]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China
  • [ 8 ] [Lan, Xujie]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Qin, Xia]Beijing Univ Technol, Dept Environm Engn, 100 Pingleyuan, Beijing 100124, Peoples R China;;

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2024

Volume: 353

8 . 6 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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