Chlorinated　volatile　organic　compounds　come　from　a　wide　range　of　sources　and　are　highly　toxic,　posing　a　serious　threat　to　biological　health　and　the　environment.　Herein,　a　high-efficiency　and　energy-saving　photothermal　synergistic　catalytic　oxidation　method　was　developed　for　the　removal　of　1,2-dichloroethane　(1,2-DCE).　Compared　to　traditional　thermocatalysis,　the　1,2-DCE　conversion　over　Ru-U6S　in　photothermal　synergistic　catalysis　at　340　degrees　C　increased　by　approximately　44%　not　only　reducing　energy　consumption　but　also　avoiding　the　instability　of　MOF　structure　caused　by　high　reaction　temperature.　The　excellent　photothermal　catalytic　oxidation　activity　was　derived　from　the　synergistic　effect　of　photo-　and　thermocatalysis.　Ru-U6S　demonstrated　excellent　1,2-DCE　adsorption　capacity　and　stronger　light　utilization　and　could　produce　more　reactive　oxygen　species　((OH)-O-center　dot　and　O-center　dot(2)-)　after　light　illumination,　which　participated　in　the　oxidation　reaction,　promoting　the　release　of　the　active　site　of　the　catalyst.　The　results　of　H2O-TPD　and　NH3-DRIFTS　exhibited　that　the　use　of　S-containing　ligands　in　the　synthesis　process　increased　the　hydroxyl　groups　and　Br　&　oslash;nsted　acid　sites,　significantly　improved　the　selectivity　of　CO2　and　HCl　in　the　oxidation　process,　and　reduced　the　release　of　chlorine-containing　byproducts.　This　work　provides　a　high-efficiency　and　energy-saving　strategy　for　removing　chlorinated　volatile　organic　compounds　and　increasing　the　selectivity　of　ideal　products　directly　with　MOFs　directly.