The　low-carbon　and　friendly　alkali-activated　cementitious　(AACM)　grouting　material　has　a　broad　application　potential　in　the　field　of　grouting　engineering　due　to　its　excellent　workability　and　higher　early　strength　and　is　expected　to　replace　cement　grouting　material　in　the　future.　In　this　study,　an　AACM　grouting　material　using　electrolytic　graphene　oxide　(EGO)　synergistic　ground　granulated　blast-furnace　slag　(GGBS)-fly　ash　(FA)-rice　husk　ash　(RHA)　solid　waste　was　proposed.　The　optimal　ratio　was　0.025　%　EGO,　8.13　%　FA,　26.6　%　RHA,　and　65.27　%　GGBS,　which　determined　by　the　Analytic　Hierarchy　Process　(AHP),　Entropy　Weight　Method　(EWP),　and　Technique　for　Order　of　Preference　by　Similarity　to　Ideal　Solution　(TOPSIS)　methods.　A　systematic　evaluation　of　the　mechanical　properties　and　impermeability　of　the　proposed　AACM　grouting　material　was　conducted　by　macro　experiments　(compressive　strength,　flexural　strength　and　permeability)　and　micro　experiments　(XRD,　SEM-EDS,　Fourier　Transform　Infrared　Spectrometer　(FTIR)　and　Thermogravimetry　Analysis　(TG)).　The　results　show　that　the　increment　of　compressive　strength　and　flexural　strength　for　AACM　grouting　material　with　0.025　%　EGO　compared　to　the　cement　water-glass　grouting　material　were　161.2　%　and　2.9　%,　respectively,　at　7-day.　While　the　permeability　coefficient　compared　to　AACM　grouting　material　without　EGO　decreased　by　43.9　%.　The　XRD　results　show　that　the　EGO　reduced　the　intensity　of　AACM　grouting　material　diffraction　peaks,　and　FTIR　analysis　reveals　that　EGO　increased　the　visibility　of　O-C-O　characteristic　peaks.　These　confirmed　that　EGO　could　enhance　the　degree　of　alkali　activation　reaction.　The　TG　results　indicate　that　the　addition　of　EGO　promoted　the　formation　of　carbonates,　which　strengthen　the　mechanical　properties　of　AACM　grouting　material.　The　SEM-EDS　results　demonstrate　that　EGO　increased　the　Ca/Si　ratio,　promoted　the　formation　of　highly　polymerized　hydration　products.