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Abstract:
Since Pb-containing electronic products were banned in 2006, the predominant substitute for Sn-Pb solder was hypoeutectic Sn3.0Ag0.5Cu (SAC305), which has been extensively utilized in contemporary. In recent years, there has been a surge in interest towards Sn-based lead-free composite solder because of their exceptional mechanical properties and service performance. Carbon-based particles, as a reinforcing material, exhibit commendable mechanical and chemical stability, high strength, temperature resistance, and other superior properties. Numerous researchers have utilized nickel as a coating agent to enhance the interfacial compatibility between carbon-based materials and Sn matrix. In this work, we examined the impact of nickel-coated graphite (GR@Ni) and nickel-coated carbon fiber (CF@Ni) on the microstructure and properties of SAC305 solder. The findings revealed that the GR@Ni tended to rise to the surface of the solder owing to a density mismatch with the Sn matrix, thereby leading to a heterogeneous microstructure. The microstructure of the micro-bump was found to contain Ni-Sn intermetallic compounds (IMC), which led to an enhancement in the hardness of the Sn matrix by refining the eutectic Ag3Sn network. In contrast, CF@Ni was uniformly distributed within the micro-bump, resulting in a reduction of similar to 30% in the interfacial IMC thickness and an increase in hardness in the CF@Ni composite solder. However, it was observed that the incorporation of CF@Ni exceeding 4 wt.% resulted in an increase in the thickness of interfacial IMC and a sharp decrease in hardness due to the presence of residual flux-induced pores. Therefore, it is recommended to limit the additional amount of CF@Ni to within the range of 0 similar to 3 wt.%.
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Source :
2023 24TH INTERNATIONAL CONFERENCE ON ELECTRONIC PACKAGING TECHNOLOGY, ICEPT
ISSN: 2836-9734
Year: 2023
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 8
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