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Author:

Bai, Zuxue (Bai, Zuxue.) | Xie, Yawei (Xie, Yawei.) | Wei, Xuechun (Wei, Xuechun.) | Zhou, Liqin (Zhou, Liqin.) | Bao, Jingyu (Bao, Jingyu.) | Tang, Rongshuo (Tang, Rongshuo.) | Wen, Yanxuan (Wen, Yanxuan.) | Zhao, Zhongxing (Zhao, Zhongxing.) | Deng, Jiguang (Deng, Jiguang.) | Zhao, Zhenxia (Zhao, Zhenxia.)

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EI Scopus SCIE

Abstract:

Great disparity in crystal size and incompatibility in crystal interface of catalysts lead to low catalytic activity, restricting its application for antibiotic degradation. Herein, a dual regulation strategy via intrinsic ion interpenetration was proposed to engineer multifunctional nano-interfacial BiFeVO4/NH2-MIL-88B(Fe-Bi) (BFV/NMFB) catalysts for efficient photo-Fenton-like catalytic degradation OTC. These multifunctional nano-interfaces (Fe-O-Bi) with abundant vacancy defects enhanced electrical conductivity, broadened light absorption and narrowed band gap. Furthermore, the strong interface bonds enhanced H2O2 adsorption and activation, accelerated photogenerated carrier separation/transfer and promoted Fe3+/Fe2+ redox activity. These properties gave an excellent synergistic effect of photo and Fenton-like catalysis (synergy factor up to 4.6) via changing photocurrent transfer pathway and interfacial adsorption-activation mechanism. Therefore, the designed BFV/NMFB exhibited superior photo-Fenton-like catalytic activity (ka = 189 mol‧mg−1‧min−1), about 3.6–58 times higher than these of reported catalysts. The proposed strategy provided a promising method for the design of MOFs composition for application of antibiotic degradation. © 2024 Elsevier B.V.

Keyword:

Antibiotics Bioremediation Nanoclay Redox reactions Bismuth alloys Catalytic oxidation Bismuth compounds Photocatalytic activity Photodegradation

Author Community:

  • [ 1 ] [Bai, Zuxue]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 2 ] [Xie, Yawei]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 3 ] [Wei, Xuechun]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 4 ] [Zhou, Liqin]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 5 ] [Bao, Jingyu]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 6 ] [Tang, Rongshuo]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 7 ] [Wen, Yanxuan]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 8 ] [Zhao, Zhongxing]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China
  • [ 9 ] [Deng, Jiguang]Department of Chemical Engineering, Faculty of Environment and Life, Beijing University of Technology, Beijing; 100124, China
  • [ 10 ] [Zhao, Zhenxia]Key Laboratory of New Low-carbon Green Chemical Technology, Education Department of Guangxi Zhuang Autonomous Region, State Key Laboratory of Featured, Metal Materials and Life-cycle Safety for Composite Structures, School of Chemistry and Chemical Engineering, Guangxi University, Nanning; 530004, China

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2025

Volume: 361

2 2 . 1 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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