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Author:

Tang, R. (Tang, R..) | Cui, S. (Cui, S..) | Yang, F. (Yang, F..) | Wang, Z. (Wang, Z..)

Indexed by:

Scopus

Abstract:

Nano hydrated calcium silicate / polycarboxylate copolymer (C-S-H / PCE) crystal nucleus suspension is a new type of early strength agent for cement concrete. It can shorten the cement hydration induction period and promote the development of early strength of cement through crystal seed nucleation. This article investigated the effect of PCE dosage on the grain size, morphology, and PCE actual combined dosage of nano C-S-H / PCE using dynamic light scattering (DLS), electron transmission microscopy (TEM), organic carbon analyzer (TOC), and thermogravimetric analysis (TGA) during the synthesis process. The effects of different dosages of PCE on the hydration heat release rate, flowability, and early strength of cement with nano C-S-H / PCE seeds were also investigated. The results show that when the PCE dosage accounted for less than 5. 0% of the mass fraction of nano C-S-H / PCE seeds suspension, the average particle size of nano C-S-H / PCE seeds gradually decreases with the increase of PCE dosage, and the agglomeration situation improves, gradually presenting a clear tin foil like morphology. When the amount of PCE increases to 10. 0%, there is little change in the particle size and morphology of the nano C-S-H / PCE seeds. TOC and TGA tests show that when the PCE dosage is 5. 0%, it basically reaches saturation adsorption capacity on C-S-H. Therefore, excessive PCE will reduce the promoting effect of nano C-S-H / PCE seeds on the hydration heat release and early strength of cement. © 2024 Bulletin of the Chinese Ceramic Society Press. All rights reserved.

Keyword:

early strength polycarboxylate superplasticizer nano seed calcium silicate hydrate adsorption cement hydration

Author Community:

  • [ 1 ] [Tang R.]State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Sciences Research, Beijing, 100041, China
  • [ 2 ] [Tang R.]College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 3 ] [Cui S.]College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Yang F.]State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Sciences Research, Beijing, 100041, China
  • [ 5 ] [Wang Z.]State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Sciences Research, Beijing, 100041, China
  • [ 6 ] [Wang Z.]College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China

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Source :

Bulletin of the Chinese Ceramic Society

ISSN: 1001-1625

Year: 2024

Issue: 9

Volume: 43

Page: 3128-3136and3202

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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