The　quinuclidine　(Qu)-catalyzed　activation　of　acylhydrazines　to　afford　the　corresponding　acyl　radicals　remains　an　unmet　challenge.　To　address　this　challenge,　we　report　a　synergistic　strategy　by　combining　electro-oxidation　with　Qu-based　HAT　catalysis.　Enabled　by　this　strategy,　the　electrochemical　Minisci　acylation　of　N-heterocycles　with　acylhydrazines　was　realized　for　the　first　time.